DSpace :: Browsing by Author "Camadanli, S."

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Homopolymerization of ethylene, 1-hexene, styrene and copolymerization of styrene with 1,3-cyclohexadiene using (η5- tetramethylcyclopentadienyl)dimethylsilyl(N-Ar')amido-TiCl2/MAO (Ar'=6-(2-(diethylboryl)phenyl)pyrid-2-yl, biphen-3-yl)
(Basel : MDPI AG, 2011) Camadanli, S.; Decker, U.; Kühnel, C.; Reinhardt, I.; Buchmeiser, M.R.
The propensity of a half-sandwich (η55- tetramethylcyclopentadienyl) dimethylsilylamido TiIV-based catalyst bearing an auxiliary diethylboryl-protected pyridyl moiety (Ti-8), activated by methylaluminoxane (MAO) to homopolymerize α-olefins such as ethylene, 1-hexene and styrene as well as to copolymerize styrene with 1,3-cyclohexadiene is described. The reactivity of Ti-8 was investigated in comparison to a 6-(2-(diethylboryl)phenyl)pyrid-2-yl-free analogue (Ti-3).