Browsing by Author "Juvé, V."

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    Ultrafast inter-ionic charge transfer of transition-metal complexes mapped by femtosecond x-ray powder diffraction
    (Les Ulis : EDP Sciences, 2013) Zamponi, F.; Freyer, B.; Juvé, V.; Stingl, J.; Woerner, M.; Chergui, M.; Elsaesser, T.
    Transient electron density maps are derived from x-ray diffraction patterns of photoexcited [Fe(bpy)3]2+(PF6 -)2 powder. Upon photoexcitation, the 5T 2 quintet state reveals a charge transfer from the PF 6- ions and from the Fe atoms to neighboring bpy units. The charge transfer from the Fe points to a partial and weak charge-transfer character of this state.