Browsing by Author "Wittmar, Matthias"
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- ItemCorrosion inhibiting cerium compounds for chromium-free corrosion protective coatings on AA 2024(Saarbrücke : Leibniz-Institut für Neue Materialien, 2007) Schem, Michael; Schmidt, Thomas; Caparrotti, Hinka; Wittmar, Matthias; Veith, MichaelDue to the upcoming ban of chromium-containing corrosion protection coatings in the near future, there is a worldwide effort to find a replacement for chromium as a corrosion inhibitor that also exhibits self-healing properties in scratches but without the negative efects like health and environmental hazards. In the present study promising results to achieve this goal are shown by using cerium compounds incorporated into an organic-inorganic hybrid material produced by the sol-gel process. Cerium compounds like cerium nitrate, cerium nitrate plus acetylacetonate, cerium acetylacetonate, and cerium sulphate were incorporated in sol-gel coating systems. The corrosion protection properties of these coatings were determined by means of Electrochemical Impedance Spectroscopy (EIS) and in a conventional salt spray test. Furthermore, the leaching behaviour of the coatings was examined via Optical Emission Spectrometry (OES). Significant hints for self healing properties were obtained with a hybrid system doped with cerium nitrate in combination with acetylacetone.
- ItemA new approach for a slurry based coating system for the prevention of high-temperature oxidation(Saarbrücken : Leibniz-Institut für Neue Materialien, 2010) Aslan, Mesut; Wittmar, Matthias; Bolz, Henning; Veith, Michael[no abstract available]
- ItemTranslucent UV light absorbant coatings for wood(Saarbrücke : Leibniz-Institut für Neue Materialien, 2009) Ullrich, Alfred; Reinhard, Bernd; Wittmar, MatthiasEfficient protection of fast growing domestic woods against the effects of weathering and UV irradiation is of increased significance to obtain improved dimensional stability and durability comparable to tropical wood. To advance the properties of those woods, a combined treatment process was developed. First, samples of pine sapwood were impregnated by project partners in the University of Göttingen to improve the dimensional stability and to avoid fungal infection of the wood, then a coating containig zinc oxide nanoparticles was applied on the impregnated wood samples at INM. Due to the UV light absorption of zinc oxide nanoparticles, the coated wood substrates are distinguished by enhanced colour stability. Together with the impregnation the coating prevents wood from deterioration by UV-irradiation and changing climates while retaining optical appearance. The water-repellent properties of the coatings interfered with the impregnation and reduced the ingress of water. This resulted in a stabilising reduction of the swelling and shrinking and avoided the formation of cracks in both wood and coating. The improved characteristics were demonstrated by artificial weathering. A prototype of an impregnated and coated window has been manufactured and is currently exposed to outdoor weathering.