Browsing by Author "Xua, Jian-Xing"

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    Rhodium-catalyzed borylative carbon monoxide reduction to gem-diborylmethane
    (Amsterdam [u.a.] : Elsevier, 2021) Xua, Jian-Xing; Wu, Fu-Peng; Wu, Xiao-Feng
    Herein, we developed a rhodium-catalyzed reduction of CO with bis(pinacolato)diboron (B2pin2) under atmospheric pressure of CO with silane as the hydride source, gem-diborylmethane [H2C(Bpin)2] as a versatile and fundamental C1 compound can be formed. Notably, this is the first example on transition metal-catalyzed borylation of CO. © 2020 The Author(s)