Geowissenschaften

Permanent URI for this collection

https://oa.tib.eu/renate/handle/123456789/240

Browse

Now showing 1 - 20 of 1634

The feedback of midlatitude waves onto the Hadley cell in a simple general circulation model
(Milton Park : Taylor & Francis, 1996) Becker, E.; Schmitz, G.; Geprägs, R.
We present self-consistent comparisons of axissymmetric and 3-dimensional simulations of the tropospheric circulation under idealized physical conditions. These reveal a feedback of transient eddies onto the Hadley circulation which, first, strongly depends on equatorial heating and, second, is in case of realistic heating quite different from prescribed eddy forcing. A quantitative estimation for the eddy-induced mixing of vorticity into the poleward flow of the Hadley cell is given. The proposed relation is in accordance with observations. It is derived from the computational result that eddy momentum flux convergence is of the same order as the equatorward flux of relative vorticity generated by the Hadley circulation. Evaluation of the local budgets of sensible heat gives rise to a clear picture of how the poleward heat transports due to Hadley circulation and transient eddies interlock. This mechanism is found to be essential for an interpretation of the eddy feedback.
The rôle of orographically and thermally forced stationary waves in the causation of the residual circulation
(Milton Park : Taylor & Francis, 1999) Becker, E.; Schmitz, G.
Several experiments performed with an idealized troposphere–stratosphere GCM are comparedto estimate the impact of orography and prescribed local heat sources on the residual circulationin the northern winter stratosphere. It is found that only the combined action of orographicand thermal wave forcing in northern midlatitudes is capable of inducing a residual circulationreaching continuously from tropical to polar latitudes at stratospheric altitudes. Intensificationsof the residual circulation in response to modified forcing of stationary waves are generallyassociated with, firstly, a reduced polar night jet accompanied by enhanced easterlies inlow and summer hemispheric latitudes and, secondly, substantial warming of the polar nightstratosphere completely compensated by cooling in the tropics and subtropics.
Very low ozone episodes due to polar vortex displacement
(Milton Park : Taylor & Francis, 2000) James, P.M.; Peters, D.; Waugh, D.W.
The large-scale ozone distribution over the northern hemisphere undergoes strong fluctuationseach winter on timescales of up to a few weeks. This is closely linked to changes in the stratosphericpolar vortex, whose shape, intensity and location vary with time. Elliptical diagnosticparameters provide an empirical description of the daily character of the polar vortex. Theseparameters are used as an objective measure to define two characteristic wintertime vortexdisplacements, towards northern Europe and Canada, respectively. The large-scale structuresin both the stratosphere and troposphere and the 3D ozone structures are determined for bothvortex displacement scenarios. A linear ozone transport model shows that the contribution ofhorizontal ozone advection dominates locally in the middle stratosphere. Nevertheless, thelargest contribution is due to vertical advection around the ozone layer maximum. The findingsare in agreement with an EOF analysis which reveals significant general modes of ozone variabilitylinked to polar vortex displacement and to phase-shifted large-scale tropospheric waves.When baroclinic waves travel through the regions of vortex-related ozone reduction, the combinedeffect is to produce transient synoptic-scale areas of exceptionally low ozone; namelydynamically induced strong ozone mini-holes.
Grundlagen der lasergestützten vor-Ort Bodenanalytik : Thema: Grundlegende Untersuchungen zur Diodenlaser-Raman-Sensorik für die organische Spurenanalytik von Böden ; Abschlußbericht
(Hannover : Technische Informationsbibliothek (TIB), 2000) Hill, Wieland; Kostrewa, S.; Viets, C.; Kahl, M.; Voges, E.
[no abstract available]
Untersuchungen zur Verwendung von Ergebnissen verschiedener Klimamodelltypen als Antrieb in Ökosystemmodellen : Abschlußbericht zum Forschungsprojekt
(Hannover : Technische Informationsbibliothek (TIB), 2000) Werner, P.C.; Bürger, G.; Gerstengarbe, F.-W.
[no abstract available]
Overview of the international project on biogenic aerosol formation in the boreal forest (BIOFOR)
(Milton Park : Taylor & Francis, 2001) Kulmala, M.; Hämeri, K.; Aalto, P.P.; Mäkelä, J.M.; Pirjola, L.; Nilsson, E. Douglas; Buzorius, G.; Rannik, Ü.; Dal Maso, M.; Seidl, W.; Hoffman, T.; Janson, R.; Hansson, H.-C.; Viisanen, Y.; Laaksonen, A.; O’dowd, C.D.
Aerosol formation and subsequent particle growth in ambient air have been frequently observed at a boreal forest site (SMEAR II station) in Southern Finland. The EU funded project BIOFOR (Biogenic aerosol formation in the boreal forest) has focused on: (a) determination of formation mechanisms of aerosol particles in the boreal forest site; (b) verification of emissions of secondary organic aerosols from the boreal forest site; and (c) quantification of the amount of condensable vapours produced in photochemical reactions of biogenic volatile organic compounds (BVOC) leading to aerosol formation. The approach of the project was to combine the continuous measurements with a number of intensive field studies. These field studies were organised in three periods, two of which were during the most intense particle production season and one during a non-event season. Although the exact formation route for 3 nm particles remains unclear, the results can be summarised as follows: Nucleation was always connected to Arctic or Polar air advecting over the site, giving conditions for a stable nocturnal boundary layer followed by a rapid formation and growth of a turbulent convective mixed layer closely followed by formation of new particles. The nucleation seems to occur in the mixed layer or entrainment zone. However two more prerequisites seem to be necessary. A certain threshold of high enough sulphuric acid and ammonia concentrations is probably needed as the number of newly formed particles was correlated with the product of the sulphuric acid production and the ammonia concentrations. No such correlation was found with the oxidation products of terpenes. The condensation sink, i.e., effective particle area, is probably of importance as no nucleation was observed at high values of the condensation sink. From measurement of the hygroscopic properties of the nucleation particles it was found that inorganic compounds and hygroscopic organic compounds contributed both to the particle growth during daytime while at night time organic compounds dominated. Emissions rates for several gaseous compounds was determined. Using four independent ways to estimate the amount of the condensable vapour needed for observed growth of aerosol particles we get an estimate of 2–10×107 vapour molecules cm−3. The estimations for source rate give 7.5–11×104 cm−3 s−1. These results lead to the following conclusions: The most probable formation mechanism is ternary nucleation (water-sulphuric acid-ammonia). After nucleation, growth into observable sizes (~3 nm) is required before new particles appear. The major part of this growth is probably due to condensation of organic vapours. However, there is lack of direct proof of this phenomenon because the composition of 1–5 nm size particles is extremely difficult to determine using the present state-of-art instrumentation.
Emission fluxes and atmospheric degradation of monoterpenes above a boreal forest: Field measurements and modelling
(Milton Park : Taylor & Francis, 2001) Spanke, Jörg; Rannik, Üllar; Forkel, Renate; Nigge, Walter; Hoffman, Thorsten
The contribution of monoterpenes to aerosol formation processes within and above forests is not well understood. This is also true for the particle formation events observed during the BIOFOR campaigns in Hyytiälä, Finland. Therefore, the diurnal variation of the concentrations of several biogenic volatile organic compounds (BVOCs) and selected oxidation products in the gas and particle phase were measured on selected days during the campaigns in Hyytiälä, Finland. α-pinene and Δ3-carene were found to represent the most important monoterpenes above the boreal forest. A clear vertical gradient of their concentrations was observed together with a change of the relative monoterpene composition with height. Based on concentration profile measurements of monoterpenes, their fluxes above the forest canopy were calculated using the gradient approach. Most of the time, the BVOC fluxes show a clear diurnal variation with a maximum around noon. The highest fluxes were observed for α-pinene with values up to 20 ng m−2 s−1 in summer time and almost 100 ng m−2 s−1 during the spring campaign. Furthermore, the main oxidation products from α-pinene, pinonaldehyde, and from β-pinene, nopinone, were detected in the atmosphere above the forest. In addition to these more volatile oxidation products, pinic and pinonic acid were identified in the particle phase in a concentration range between 1 and 4 ng m−3. Beside these direct measurement of known oxidation products, the chemical sink term in the flux calculations was used to estimate the amount of product formation of the major terpenes (α-pinene, β-pinene, Δ3-carene). A production rate of very low volatile oxidation products (e.g., multifunctional carboxylic) from ·OH- and O3-reaction of monoterpenes of about 1.3·104 molecules cm−3 s−1 was estimated for daylight conditions during summer time. Additionally, model calculations with the one-dimensional multilayer model CACHE were carried out to investigate the diurnal course of BVOC fluxes and chemical degradation of terpenes.
Europäische Ökosysteme 1989 - 1998: Quantitative Analyse unter Verwendung von Satelliten-Fernerkundungsdaten - Teilprojekt Modelle : Schlußbericht
(Hannover : Technische Informationsbibliothek (TIB), 2001) Cramer, Wolfgang; Lucht, Wolfgang; Bondeau, Alberte
[no abstract available]
Field measurements of hygroscopic properties and state of mixing of nucleation mode particles
(München : European Geopyhsical Union, 2002) Väkevä, M.; Kulmala, M.; Stratmann, F.; Hämeri, K.
An Ultrafine Tandem Differential Mobility Analyser (UF-TDMA) has been used in several field campaigns over the last few years. The investigations were focused on the origin and properties of nucleation event aerosols, which are observed frequently in various environments. This paper gives a summary of the results of 10 nm and 20 nm particle hygroscopic properties from different measurement sites: an urban site, an urban background site and a forest site in Finland and a coastal site in western Ireland. The data can be classified in four hygroscopic growth classes: hydrofobic, less-hygroscopic, more-hygroscopic and sea-salt. Similar classification has been earlier presented for Aitken and accumulation mode particles. In urban air, the summertime 10 nm particles showed varying less-hygroscopic growth behaviour, while winter time 10 nm and 20 nm particles were externally mixed with two different hygroscopic growth modes. The forest measurements revealed diurnal behaviour of hygroscopic growth, with high growth factors at day time and lower during night. The urban background particles had growth behaviour similar to the urban and forest measurement sites depending on the origin of the observed particles. The coastal measurements were strongly affected by air mass history. Both 10 nm and 20 nm particles were hygroscopic in marine background air. The 10 nm particles produced during clean nucleation burst periods were hydrofobic. Diurnal variation and higher growth factors of 10 nm particles were observed in air affected by other source regions. External mixing was occasionally observed at all the sites, but incidents with more than two growth modes were extremely rare.
The impact of multiphase reactions of NO2 with aromatics: A modelling approach
(München : European Geopyhsical Union, 2002) Lahoutifard, N.; Ammann, M.; Gutzwiller, L.; Ervens, B.; George, Ch.
The impact of multiphase reactions involving nitrogen dioxide (NO2) and aromatic compounds was simulated in this study. A mechanism (CAPRAM 2.4, MODAC Mechanism) was applied for the aqueous phase reactions, whereas RACM was applied for the gas phase chemistry. Liquid droplets were considered as monodispersed with a mean radius of 0.1 µm and a liquid content (LC) of 50 µg m-3. The multiphase mechanism has been further extended to the chemistry of aromatics, i.e. reactions involving benzene, toluene, xylene, phenol and cresol have been added. In addition, reaction of NO2 with dissociated hydroxyl substituted aromatic compounds has also been implemented. These reactions proceed through charge exchange leading to nitrite ions and therefore to nitrous acid formation. The strength of this source was explored under urban polluted conditions. It was shown that it may increase gas phase HONO levels under some conditions and that the extent of this effect is strongly pH dependent. Especially under moderate acidic conditions (i.e. pH above 4) this source may represent more than 75% of the total HONO/NO2 - production rate, but this contribution drops down close to zero in acidic droplets (as those often encountered in urban environments).
Untersuchungen zur chemischen Zusammensetzung der organischen Komponente des troposphärischen Aerosols : AFS-Abschlußbericht
(Hannover : Technische Informationsbibliothek (TIB), 2002) Hoffmann, Th.; Warscheid, Bettina; Nigge, Walter; Kückelmann, Ulrich
[no abstract available]
Wasserverfügbarkeit sowie ökologische, klimatische und sozioökonomische Wechselwirkungen im semiariden Nordosten Brasiliens am Beispiel der Bundesstaaten Piauí und Ceará : Fachbereich: Klimaanalyse/ -modellierung - großskaliges hydrologisches Modell ; Teilprojekt: Klimaanalyse/ -modellierung ; Vorhabensbezeichnung: Analyse und Modellierung der raumzeitlichen klimatischen Bedingungen im Nordosten Brasiliens zur Entwicklung von Klimaszenarien im Verbundprojekt WAVES - Water Availability, Vulnerability of Ecosystems and Society in the Northeast of Brazil ; Abschlussbericht
(Hannover : Technische Informationsbibliothek (TIB), 2002) Gerstengarbe, Friedrich-Wilhelm; Werner, P.C.; Böhm, U.; Kücken, M.; Hauffe, D.
[no abstract available]
Integrierte Modellierung der Wirkungskette von Klima, Wasserverfügbarkeit und Migrationsdynamik in Ceará und Piauí, unter besonderer Berücksichtigung von Rückkopplungen und räumlichen Variabilitäten und Szenarienanalysen : Wasserverfügbarkeit sowie ökologische, klimatische und sozioökonomische Wechselwirkungen im semiariden Nordosten Brasiliens ; Verbundprojekt WAVES ; Schlussbericht Fachbereich Integrierte Modellierung
(Hannover : Technische Informationsbibliothek (TIB), 2002) Krol, M.S.; Jaeger, A.; Bronstert, A.
[no abstract available]
Particle formation at a continental background site: Comparison of model results with observations
(München : European Geopyhsical Union, 2003) Uhrner, U.; Birmili, W.; Stratmann, F.; Wilck, M.; Ackermann, I.J.; Berresheim, H.
At Hohenpeissenberg (47° 48' N, 11° 07' E, 988 m asl), a rural site 200--300~m higher than the surrounding terrain, sulphuric acid concentrations, particle size distributions, and other trace gas concentrations were measured over a two and a half year period. Measured particle number concentrations and inferred particle surface area concentrations were compared with box-model simulations for 12 carefully selected data sets collected during the HAFEX experiment (Birmili et al., 2003). The 12 cases were selected after meteorological and aerosol dynamical criteria in order to justify the use of a box-model. The aerosol model included a binary sulphuric acid water nucleation scheme. Calculated nucleation rates were corrected with a factor to match measured and calculated particle number concentrations. For the investigated 12 data sets, the correction factors were smallest for measurements made under stable thermal stratification and low wind conditions, i.e. conditions that are frequently encountered during winter. Correction factors were largest for measurements made under strong convective conditions. Our comparison of measured and simulated particle size distributions suggests that the particle formation process maybe strongly influenced by mixing processes driven by thermal convection and/or wind sheer.
Hygroscopic properties of different aerosol types over the Atlantic and Indian Oceans
(München : European Geopyhsical Union, 2003) Maßling, A.; Wiedensohler, A.; Busch, B.; Neusüß, C.; Quinn, P.; Bates, T.; Covert, D.
Hygroscopic properties of atmospheric particles were studied in the marine tropospheric boundary layer over the Atlantic and Indian Oceans during two consecutive field studies: the Aerosols99 cruise (Atlantic Ocean) from 15 January to 20 February 1999, and the INDOEX cruise (Indian Ocean Experiment) from 23 February to 30 March 1999. The hygroscopic properties were compared to optical and chemical properties, such as absorption, chemical inorganic composition, and mass concentration of organic and elemental carbon, to identify the influence of these parameters on hygroscopicity. During the two field studies, four types of aerosol-sampling instruments were used on board the NOAA (National Oceanic and Atmospheric Administration) Research Vessel Ronald H. Brown: Hygroscopicity Tandem Differential Mobility Analyzer (HTDMA), seven-stage cascade impactor, two-stage cascade impactor, and Particle Soot Absorption Photometer (PSAP). The HTDMA was used to determine the hygroscopic properties of atmospheric particles at initial dry sizes (Dp) of 50, 150, and 250 nm and at relative humidities (RH) of 30, 55, 75, and 90%. Simultaneously, a seven-stage cascade impactor of which 3 stages were in the sub-mm size range was used to determine the molar composition of the major inorganic ions such as ammonium and sulfate ions. A two-stage cascade impactor (1 in the sub-mm size range, 1 in the sup-mm size range) was used to determine the mass concentration of organic and elemental carbon. The PSAP was used (at a wavelength of 565 nm) to measure the light absorption coefficient of the aerosol. During the two field studies, air masses of several different origins passed the ship's cruise path. The occurrence of different air masses was classified into special time periods signifying the origin of the observed aerosol. All time periods showed a group of particles with high hygroscopic growth. The measured average hygroscopic growth factors defined by the ratio of dry and wet particle diameter at 90% RH ranged from 1.6 to 2.0, depending on the dry particle size and on the type of air mass. Particles with low hygroscopic growth occurred only when continentally influenced air masses arrived at the ship's position. Distinctions in hygroscopic growth of particles of different air masses were more significant for small relative humidities (30% or 55% RH). High concentrations of elemental carbon corresponded with high light absorption coefficients and with the occurrence of less-hygroscopic and nearly hydrophobic particle fractions in the hygroscopic growth distributions. A key finding is that clean marine air masses that had no land contact for five to six days could clearly be distinguished from polluted air masses that had passed over a continent several days before reaching the ship.
Dependence of solar radiative forcing of forest fire aerosol on ageing and state of mixture
(München : European Geopyhsical Union, 2003) Fiebig, M.; Stohl, A.; Wendisch, M.; Eckhardt, S.; Petzold, A.
During airborne in situ measurements of particle size distributions in a forest fire plume originating in Northern Canada, an accumulation mode number mean diameter of 0.34 mm was observed over Lindenberg, Germany on 9 August 1998. Realizing that this is possibly the largest value observed for this property in a forest fire plume, scenarios of plume ageing by coagulation are considered to explain the observed size distribution, concluding that the plume dilution was inhibited in parts of the plume. The uncertainties in coagulation rate and transition from external to internal mixture of absorbing forest fire and non-absorbing background particles cause uncertainties in the plume's solar instantaneous radiative forcing of 20-40% and of a factor of 5-6, respectively. Including information compiled from other studies on this plume, it is concluded that the plume's characteristics are qualitatively consistent with a radiative-convective mixed layer.
First observations of noctilucent clouds by lidar at Svalbard, 78° N
(München : European Geopyhsical Union, 2003) Höffner, J.; Fricke-Begemann, C.; Lübken, F.-J.
In summer 2001 a potassium lidar was installed near Longyearbyen (78° N) on the north polar island of Spitsbergen which is part of the archipelago Svalbard. At the same place a series of meteorological rockets ("falling spheres", FS) were launched which gave temperatures from the lower thermosphere to the stratosphere. The potassium lidar is capable of detecting noctilucent clouds (NLCs) and of measuring temperatures in the lower thermosphere, both under daylight conditions. In this paper we give an overview on the NLC measurements (the first at this latitude) and compare the results with temperatures from meteorological rockets which have been published recently (Lübken and Mülleman, 2003) NLCs were observed from 12 June (the first day of operation) until 12 August when a period of bad weather started. When the lidar was switched on again on 26 August, no NLC was observed. The mean occurrence frequency in the period 12 June -- 12 August ("lidar NLC period") is 77%. The mean of all individual NLC peak altitudes is 83.6 km (variability: 1.1 km). The mean peak NLC altitude does not show a significant variation with season. The average top and bottom altitude of the NLC layer is 85.1 and 82.5 km, respectively, with a variability of ~1.2 km. The mean of the maximum volume backscatter coefficient bmax at our wavelength of 770 nm is 3.9 x 10-10/m/sr with a large variability of ±3.8 x 10-10/m/sr. Comparison of NLC characteristics with measurements at ALOMAR (69° N) shows that the peak altitude and the maximum volume backscatter coefficient are similar at both locations but NLCs occur more frequently at higher latitudes. Simultaneous temperature and NLC measurements are available for 3 flights and show that the NLC layer occurs in the lower part of the height range with super-saturation. The NLC peak occurs over a large range of degree of saturation (S) whereas most models predict the peak at S = 1. This demonstrates that steady-state considerations may not be applicable when relating individual NLC properties to background conditions. On the other hand, the mean variation of the NLC appearance with height and season is in agreement with the climatological variation of super-saturation derived from the FS temperature measurements.
New-particle formation events in a continental boundary layer: First results from the SATURN experiment
(München : European Geopyhsical Union, 2003) Stratmann, F.; Siebert, H.; Spindler, G.; Wehner, B.; Althausen, D.; Heintzenberg, J.; Hellmuth, O.; Rinke, R.; Schmieder, U.; Seidel, C.; Tuch, T.; Uhrner, U.; Wiedensohler, A.; Wandinger, U.; Wendisch, M.; Schell, D.; Stohl, A.
During the SATURN experiment, which took place from 27 May to 14 June 2002, new particle formation in the continental boundary layer was investigated. Simultaneous ground-based and tethered-balloon-borne measurements were performed, including meteorological parameters, particle number concentrations and size distributions, gaseous precursor concentrations and SODAR and LIDAR observations. Newly formed particles were observed inside the residual layer, before the break-up process of the nocturnal inversion, and inside the mixing layer throughout the break-up of the nocturnal inversion and during the evolution of the planetary boundary layer.
Small scale density variations of electrons and charged particles in the vicinity of polar mesosphere summer echoes
(München : European Geopyhsical Union, 2003) Rapp, M.; Lübken, F.-J.; Blix, T.A.
We present small scale variations of electron number densities and particle charge number densities measured in situ in the presence of polar mesosphere summer echoes. It turns out that the small scale fluctuations of electrons and negatively charged particles show a strong anticorrelation down to the smallest scales observed. Comparing these small scale structures with the simultaneously measured radar signal to noise profile, we find that the radar profile is well described by the power spectral density of both electrons and charged particles at the radar half wavelength (=the Bragg scale). Finally, we consider the shape of the power spectra of the observed plasma fluctuations and find that both charged particles and electrons show spectra that can be explained in terms of either neutral air turbulence acting on the distribution of a low diffusivity tracer or the fossil remnants of a formerly active turbulent region. All these results are consistent with the theoretical ideas by Rapp and Lübken (2003) suggesting that PMSE can be explained by a combination of active and fossil neutral air turbulence acting on the large and heavy charged aerosol particles which are subsequently mirrored in the electron number density distribution that becomes visible to a VHF radar when small scale fluctuations are present.
Out of Africa: High aerosol concentrations in the upper troposphere over Africa
(München : European Geopyhsical Union, 2003) Heintzenberg, J.; Hermann, M.; Theiss, D.
In the year 2000, six flights (three southbound and three northbound) of the CARIBIC project were conducted between Germany and two destinations in the southern hemisphere (Windhoek, Namibia and Cape Town, South Africa). In the present report, results on particle number concentrations are discussed in three size ranges (>4 nm, >12 nm, and >18 nm particle diameter) during the unique transequatorial Africa flights. The flights covered a total of about 80 h in May, July, and December. Thus, no claim can be made for long-term representativeness of the aerosol data. Nevertheless, they are the first upper systematic tropospheric transequatorial aerosol profiles over Africa. The average aerosol results show a broad maximum, roughly symmetrical to the equator, which compares well in latitudinal extent to a maximum of CO concentrations measured on the same flights. This export of continental surface aerosol to the upper troposphere will be dispersed on a global scale both with the easterly flow near the equator and with the westerlies in the adjacent subtropical regions. There was strong evidence of recent new particle formation before aerosol arrival at flight level, in particular during the time periods between 9:00 and 13:00 local time over Africa. Direct and indirect climate effects of the respective particulate matter remain to be investigated by future flights with the ongoing extension of the CARIBIC payload towards size-resolved measurements above 100 nm particle diameter. At the same time global chemical transport models and aerosol dynamics models need to be extended to be able to reproduce the CARIBIC findings over Africa.

Browse

Browsing Geowissenschaften by Issue Date

Results Per Page

Sort Options