Fachgebiete

Permanent URI for this community

https://oa.tib.eu/renate/handle/123456789/1

Browse

Now showing 1 - 20 of 14309

1,1,2,2-Tetra-phenyl-15-diphosphane 1-sulfide
(Chester : International Union of Crystallography, 2009) Aluri, B.R.; Peitz, S.; Wöhl, A.; Peulecke, N.; Müller, B.H.; Spannenberg, A.; Rosenthal, U.
In the title mol-ecule, C24H20P2S, the P - P bond length is 2.2263 (5) Å. The two phenyl rings attached to the three- and five-coordinated P atoms, respectively, form dihedral angles of 56.22 (5) and 71.74 (5)°.
1,1-Bis(diphenylphosphoryl)hydrazine
(Chester : International Union of Crystallography, 2018) Höhne, Martha; Aluri, Bhaskar R.; Spannenberg, Anke; Müller, Bernd H.; Peulecke, Normen; Rosenthal, Uwe
The title compound, C24H22N2O2P2, contains a diphosphazane backbone, as well as a hydrazine entity. The P—N—P diphosphazane unit and the N-amine N atom are almost coplanar, and the O atoms of the Ph2P(O) units are oriented trans to each other with respect to the P...P axis. In the crystal, centrosymmetrically related molecules are linked into dimers by pairs of N—H...O hydrogen bonds, forming rings of graph-set motif R22(10).
(+)-{1,2-Bis[(2R,5R)-2,5-diethyl-phospho-lan-1-yl]ethane- κ2 P,P′}(≠4-cyclo-octa-1,5-diene)rhodium(I) tetra-fluoridoborate
(Chester : International Union of Crystallography, 2010) Schulz, S.; Fischer, C.; Drexler, H.-J.; Heller, D.
The title compound, [Rh(C8H12)(C18H 36P2)]BF4, exhibits a rhodium(I) complex cation with a bidentate bis-phosphine ligand and a bidentate 2, 2-coordinated cyclo-octa-1,5-diene ligand. The ligands form a slightly distorted square-planar coordination environment for the Rh(I) atom. An intra-molecular P-Rh-P bite angle of 83.91 (2)° is observed. The dihedral angle between the P - Rh - P and the X - Rh - X planes (X is the centroid of a double bond) is 14.0 (1)°. The BF4 anion is disordered over two positions in a 0.515 (7):0.485 (7) ratio.
(+)-{1,2-Bis[(2R,5R)-2,5-dimethyl-phospho-lan-1-yl]ethane- κ2 P,P′}(η4-cyclo-octa-1,5-diene) rhodium(I) tetra-fluorido-borate
(Chester : International Union of Crystallography, 2010) Schulz, S.; Drexler, H.-J.; Heller, D.
The title compound, [Rh(C8H12)(C14H 28P2)]BF4, exhibits a rhodium(I) complex cation with a bidentate bis-phosphine ligand and a bidentate η2, η2-coordinated cyclo-octa-1,5-diene. Together the ligands create a slightly distorted square-planar cordination environment for the Rh(I) atom. There are three mol-ecules in the asymmetric unit and intra-molecular P - Rh - P bite angles of 82.78 (5), 82.97 (6) and 83.09 (5)° are observed. The dihedral angles between the P - Rh - P and the X - Rh - X planes (X is the centroid of a double bond) are 14.7 (1), 14.8 (1) and 15.3 (1)°. The structure exhibits disorder of one cyclo-octa-diene ligand as well as one BF4 anion.
1,7,9,10-Tetrasubstituted PMIs Accessible through Decarboxylative Bromination: Synthesis, Characterization, Photophysical Studies, and Hydrogen Evolution Catalysis
(Weinheim : Wiley-VCH, 2020) Costabel, Daniel; Skabeev, Artem; Nabiyan, Afshin; Luo, Yusen; Max, Johannes B.; Rajagopal, Ashwene; Kowalczyk, Daniel; Dietzek, Benjamin; Wächtler, Maria; Görls, Helmar; Ziegenbalg, Dirk; Zagranyarski, Yulian; Streb, Carsten; Schacher, Felix H.; Peneva, Kalina
In this work, we present a new synthetic strategy for fourfold-substituted perylene monoimides via tetrabrominated perylene monoanhydrides. X-ray diffraction analysis unveiled the intramolecular stacking orientation between the substituents and semicircular packing behavior. We observed the remarkable influence of the substituent on the longevity and nature of the excited state upon visible light excitation. In the presence of poly(dehydroalanine)-graft-poly(ethylene glycol) graft copolymers as solubilizing template, the chromophores are capable of sensitizing [Mo3S13]2− clusters in aqueous solution for stable visible light driven hydrogen evolution over three days. © 2020 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH
1-Benzyl-3-methylimidazolium bromide
(Chester : IUCr, 2020) Peppel, Tim; Wulf, Christoph; Spannenberg, Anke
[no abstract available]
1-Butyl-3-methylimidazolium tribromido(triphenylphosphane-κP)nickelate(II) butan-1-ol hemisolvate
(Chester : IUCr, 2021) Peppel, T.; Köckerling, M.
The solvated title salt, (C8H15N2)[NiBr3(P(C6H5)3)]·0.5C4H10O, was obtained in the form of single crystals directly from the reaction mixture. The molecular structure consists of separated 1-butyl-3-methylimidazolium cations, tribromido(triphenylphosphane)nickelate(II) anions and half a solvent molecule of 1-butanol, all connected via multiple hydrogen contacts to form a three-dimensional network. The co-crystallized 1-butanol molecule is disordered and adopts two orientations. The central C—C bonds of both orientations are located on an inversion centre (Wyckoff site 2b of space group P21/n). Thereby, each orientation has again two orientations with the OH group being located either on one or the other side of the C4 alkyl chain. The dried solvent-free compound exhibits a relatively low melting point (m.p. = 412 K).
[1-Dimethylsilyl-2-phenyl-3-(η5-tetramethylcyclopentadienyl) prop-1-en-1-ylκC1](n5-pentamethylcyclopentadienyl)- titanium(III)
(Chester : International Union of Crystallography, 2009) Lamač, M.; Spannenberg, A.; Arndt, P.; Rosenthal, U.
The title compound, [Ti(C10H15)(C20H 26Si)], was obtained from the reaction of [Ti{5: 1-C5Me4(CH2)}(5-C 5Me5)] with the alkynylsilane PhC2SiMe 2H. The complex crystallizes with two independent mol-ecules in the asymmetric unit, which differ in the conformation of the propenyl unit, resulting in their having opposite helicity. No inter-molecular inter-actions or inter-actions involving the Si- H bond are present. The observed geometrical parameters are unexceptional compared to known structures of the same type.
1-Diphenylphosphanyl-2-(diphenylphosphoryl)hydrazine
(Chester : IUCr, 2018) Höhne, Martha; Aluri, Bhaskar; Spannenberg, Anke; Müller, Bernd H.; Peulecke, Normen; Rosenthal, Uwe
The title compound, C24H22N2OP2, is an asymmetrically substituted hydrazine derivative bearing a phosphoryl and a phosphanyl substituent. The PNNP backbone has a torsion angle of −131.01 (8)°. In the crystal, molecules form centrosymmetric dimers by intermolecular N—H...O hydrogen bonds, which are further linked into a three-dimensional network by weak C—H...O and C—H...π interactions.
The 1-Megapixel pnCCD detector for the Small Quantum Systems Instrument at the European XFEL: system and operation aspects
(Chester : IUCr, 2021) Kuster, Markus; Ahmed, Karim; Ballak, Kai Erik; Danilevski, Cyril; Ekmedžić, Marko; Fernandes, Bruno; Gessler, Patrick; Hartmann, Robert; Hauf, Steffen; Holl, Peter; Meyer, Michael; Montaño, Jacobo; Münnich, Astrid; Ovcharenko, Yevheniy; Rennhack, Nils; Rüter, Tonn; Rupp, Daniela; Schlosser, Dieter; Setoodehnia, Kiana; Schmitt, Rüdiger; Strüder, Lothar; Tanyag, Rico Mayro P.; Ulmer, Anatoli; Yousef, Hazem
The X-ray free-electron lasers that became available during the last decade, like the European XFEL (EuXFEL), place high demands on their instrumentation. Especially at low photon energies below 1 keV, detectors with high sensitivity, and consequently low noise and high quantum efficiency, are required to enable facility users to fully exploit the scientific potential of the photon source. A 1-Megapixel pnCCD detector with a 1024 × 1024 pixel format has been installed and commissioned for imaging applications at the Nano-Sized Quantum System (NQS) station of the Small Quantum System (SQS) instrument at EuXFEL. The instrument is currently operating in the energy range between 0.5 and 3 keV and the NQS station is designed for investigations of the interaction of intense FEL pulses with clusters, nano-particles and small bio-molecules, by combining photo-ion and photo-electron spectroscopy with coherent diffraction imaging techniques. The core of the imaging detector is a pn-type charge coupled device (pnCCD) with a pixel pitch of 75 µm × 75 µm. Depending on the experimental scenario, the pnCCD enables imaging of single photons thanks to its very low electronic noise of 3 e− and high quantum efficiency. Here an overview on the EuXFEL pnCCD detector and the results from the commissioning and first user operation at the SQS experiment in June 2019 are presented. The detailed descriptions of the detector design and capabilities, its implementation at EuXFEL both mechanically and from the controls side as well as important data correction steps aim to provide useful background for users planning and analyzing experiments at EuXFEL and may serve as a benchmark for comparing and planning future endstations at other FELs.
1-Titanacyclobuta-2,3-diene-an elusive four-membered cyclic allene
(Cambridge : RSC, 2019) Reiß, Fabian; Reiß, Melanie; Bresien, Jonas; Spannenberg, Anke; Jiao, Haijun; Baumann, Wolfgang; Arndt, Perdita; Beweries, Torsten
The synthesis of an unusual 1-metalla-2,3-cyclobutadiene complex [rac-(ebthi)Ti(Me3SiC3SiMe3)] (rac-ebthi = rac-1,2-ethylene-1,1′-bis(η5-tetrahydroindenyl)), a formal metallacyclic analogue of a non-existent four-membered 1,2-cyclobutadiene, is described. By variation of the cyclopentadienyl ligand of the titanocene precursor it was possible to stabilise this highly exotic compound which selectively reacts with ketones and aldehydes to yield enynes by oxygen transfer to titanium. Analysis of the bonding and electronic structure of the metallacycle shows that the complex is best described as an unusual antiferromagnetically coupled biradicaloid system, possessing a formal Ti(iii) centre coordinated with a monoanionic radical ligand. © 2019 The Royal Society of Chemistry.
10 Jahre Transformationsverträge an der TIB – Resümee und Ausblick einer Konsortialführung
(Reutlingen : Berufsverband Information Bibliothek e. V., 2024) Bieg, Nicola; Pöche, Alexander
Sind Transformationsverträge passé? Während hierzulande gerade erst unter dem Banner des DEAL-Konsortiums ein 5-Jahres-Vertrag mit Verlagsgigant Elsevier startet, rufen Akteure aus anderen Ländern das Ende von Transformationsverträgen aus. Die Technische Informationsbibliothek (TIB) sieht sich ebenfalls mit der Frage nach der Zukunft von transformativen Vereinbarungen und damit auch vieler von ihr geführten Konsortien konfrontiert. Seit dem ersten Read & Publish-Vertrag mit der Royal Society of Chemistry aus dem Jahr 2014, hat die TIB kontinuierlich transformative Konsortialverträge mit Verlagen und Fachgesellschaften verhandelt. Abhängig von Größe und Finanzierungskonzept des Anbieters, der inhaltlichen Ausrichtung des Zeitschriftenportfolios und vieler weiterer Faktoren wurden Modelle, die zwar beide Leistungsarten vereinen, aber ansonsten durchaus heterogen sind, entwickelt und implementiert. In diesem Vortrag möchten wir ein Resümee aus 10 Jahren Erfahrung in der Verhandlung und Administration von Transformationsverträgen ziehen: Was wurde erreicht? Was waren die Herausforderungen? Was sind und waren prognostizierte und unerwartete Entwicklungen? Die Bilanz soll nicht nur der Schärfung der strategischen Ausrichtung des eigenen Konsortialgeschäfts dienen, sondern auch einen generellen Beitrag zur Bewertung von Angeboten mit Publish-Komponenten liefern und die Diskussionen dazu bereichern.
1064nm rotational Raman lidar for particle extinction and lidar-ratio profiling: Cirrus case study
(München : European Geopyhsical Union, 2016) Haarig, Moritz; Engelmann, Ronny; Ansmann, Albert; Veselovskii, Igor; Whiteman, David N.; Althausen, Dietrich
For the first time, vertical profiles of the 1064 nm particle extinction coefficient obtained from Raman lidar observations at 1058 nm (nitrogen and oxygen rotational Raman backscatter) are presented. We applied the new technique in the framework of test measurements and performed several cirrus observations of particle backscatter and extinction coefficients, and corresponding extinction-to-backscatter ratios at the wavelengths of 355, 532, and 1064 nm. The cirrus backscatter coefficients were found to be equal for all three wavelengths keeping the retrieval uncertainties in mind. The multiple-scattering-corrected cirrus extinction coefficients at 355 nm were on average about 20–30 % lower than the ones for 532 and 1064 nm. The cirrus-mean extinction-to-backscatter ratio (lidar ratio) was 31 ± 5 sr (355 nm), 36 ± 5 sr (532 nm), and 38 ± 5 sr (1064 nm) in this single study. We further discussed the requirements needed to obtain aerosol extinction profiles in the lower troposphere at 1064 nm with good accuracy (20 % relative uncertainty) and appropriate temporal and vertical resolution.
A 112 Gb/s Radiation-Hardened Mid-Board Optical Transceiver in 130-nm SiGe BiCMOS for Intra-Satellite Links
(Lausanne : Frontiers Media, 2021) Giannakopoulos, Stavros; Sourikopoulos, Ilias; Stampoulidis, Leontios; Ostrovskyy, Pylyp; Teply, Florian; Tittelbach-Helmrich, K.; Panic, Goran; Fischer, Gunter; Grabowski, Alexander; Zirath, Herbert; Ayzac, Philippe; Venet, Norbert; Maho, Anaëlle; Sotom, Michel; Jones, Shaun; Wood, Grahame; Oxtoby, Ian
We report the design of a 112 Gb/s radiation-hardened (RH) optical transceiver applicable to intra-satellite optical interconnects. The transceiver chipset comprises a vertical-cavity surface-emitting laser (VCSEL) driver and transimpedance amplifier (TIA) integrated circuits (ICs) with four channels per die, which are adapted for a flip-chip assembly into a mid-board optics (MBO) optical transceiver module. The ICs are designed in the IHP 130 nm SiGe BiCMOS process (SG13RH) leveraging proven robustness in radiation environments and high-speed performance featuring bipolar transistors (HBTs) with fT/fMAX values of up to 250/340 GHz. Besides hardening by technology, radiation-hardened-by-design (RHBD) components are used, including enclosed layout transistors (ELTs) and digital logic cells. We report design features of the ICs and the module, and provide performance data from post-layout simulations. We present radiation evaluation data on analog devices and digital cells, which indicate that the transceiver ICs will reliably operate at typical total ionizing dose (TID) levels and single event latch-up thresholds found in geostationary satellites.
14 Years of PID services at the German National Library of Science and Technology (TIB): Connected frameworks, research data and lessons learned from a National Research Library perspective
(Paris : CODATA, 2017) Kraft, Angelina; Dreyer, Britta; Löwe, Peter; Ziedorn, Frauke
In an ideal research world, any scientific content should be citable and the coherent content, as well as the citation itself, should be persistent. However, today’s scientists do not only produce traditional research papers – they produce comprehensive digital resources and collections. TIB’s mission is to develop a supportive framework for a sustainable access to such digital content – focusing on areas of engineering as well as architecture, chemistry, information technology, mathematics and physics. The term digital content comprises all digitally available resources such as audiovisual media, databases, texts, images, spreadsheets, digital lab journals, multimedia, 3D objects, statistics and software code. In executing this mission, TIB provides services for the management of digital content during ongoing and for finished research. This includes: • a technical and administrative infrastructure for indexing, cataloguing, DOI registration and licensing for text and digital objects, namely the TIB DOI registration which is active since 2005, • the administration of the ORCID DE consortium, an institutional network fostering the adoption of ORCID across academic institutions in Germany, • training and consultancy for data management, complemented with a digital repository for the deposition and provision of accessible, traceable and citable research data (RADAR), • a Research and Development Department where innovative projects focus on the visualization and the sustainable access to digital information, and • the development of a supportive framework within the German research data community which accompanies the life cycle of scientific knowledge generation and transfer. Its goal is to harmonize (meta)data display and exchange primarily on a national level (LEIBNIZ DATA project).
A ∼15 kpc outflow cone piercing through the halo of the blue compact metal-poor galaxy SBS 0335-052E
(Les Ulis : EDP Sciences, 2023) Herenz, E.C.; Inoue, J.; Salas, H.; Koenigs, B.; Moya-Sierralta, C.; Cannon, J.M.; Hayes, M.; Papaderos, P.; Östlin, G.; Bik, A.; Le Reste, A.; Kusakabe, H.; Monreal-Ibero, A.; Puschnig, J.
Context. Outflows from low-mass star-forming galaxies are a fundamental ingredient for models of galaxy evolution and cosmology. Despite seemingly favourable conditions for outflow formation in compact starbursting galaxies, convincing observational evidence for kiloparsec-scale outflows in such systems is scarce. Aims. The onset of kiloparsec-scale ionised filaments in the halo of the metal-poor compact dwarf SBS 0335-052E was previously not linked to an outflow. In this paper we investigate whether these filaments provide evidence for an outflow. Methods. We obtained new VLT/MUSE WFM and deep NRAO/VLA B-configuration 21 cm data of the galaxy. The MUSE data provide morphology, kinematics, and emission line ratios of Hβ/Hα and [O ¯III]λ5007/Hα of the low surface-brightness filaments, while the VLA data deliver morphology and kinematics of the neutral gas in and around the system. Both datasets are used in concert for comparisons between the ionised and the neutral phase. Results. We report the prolongation of a lacy filamentary ionised structure up to a projected distance of 16 kpc at SBHα = 1.5 - 10-18 erg s cm-2 arcsec-2. The filaments exhibit unusual low Hα/Hβ 2.4 and low [Oa ¯III]/Hα ∼ 0.4 - 0.6 typical of diffuse ionised gas. They are spectrally narrow (∼20 km s-1) and exhibit no velocity sub-structure. The filaments extend outwards from the elongated Ha ¯I halo. On small scales, the NHI peak is offset from the main star-forming sites. The morphology and kinematics of Ha ¯I and Ha ¯II reveal how star-formation-driven feedback interacts differently with the ionised and the neutral phase. Conclusions. We reason that the filaments are a large-scale manifestation of star-formation- driven feedback, namely limb-brightened edges of a giant outflow cone that protrudes through the halo of this gas-rich system. A simple toy model of such a conical structure is found to be commensurable with the observations.
16.3 w peak‐power pulsed all‐diode laser based multi‐wavelength master‐oscillator power‐amplifier system at 964 nm
(Basel : MDPI, 2021) Vu, Thi Nghiem; Tien, Tran Quoc; Sumpf, Bernd; Klehr, Andreas; Fricke, Jörg; Wenzel, Hans; Tränkle, Günther
An all-diode laser-based master oscillator power amplifier (MOPA) configuration for the generation of ns-pulses with high peak power, stable wavelength and small spectral line width is presented. The MOPA emits alternating at two wavelengths in the spectral range between 964 nm and 968 nm, suitable for the detection of water vapor by absorption spectroscopy. The monolithic master oscillator (MO) consists of two slightly detuned distributed feedback laser branches, whose emission is combined in a Y-coupler. The two emission wavelengths can be adjusted by varying the current or temperature to an absorption line and to a non-absorbing region. The power amplifier (PA) consists of a ridge-waveguide (RW) section and a tapered section, monolithically integrated within one chip. The RW section of the PA acts as an optical gate and converts the continuous wave input beam emitted by the MO into a sequence of short optical pulses, which are subsequently amplified by the tapered section to boost the output power. For a pulse width of 8 ns, a peak power of 16.3 W and a side mode suppression ratio of more than 37 dB are achieved at a repetition rate of 25 kHz. The measured spectral width of 10 pm, i.e., 0.1 cm−1, is limited by the resolution of the optical spectrum analyzer. The generated pulses emitting alternating at two wavelengths can be utilized in a differential absorption light detection and ranging system.
168-195 GHz Power Amplifier with Output Power Larger Than 18 dBm in BiCMOS Technology
(New York, NY : IEEE, 2020) Ali, Abdul; Yun, Jongwon; Giannini, Franco; Ng, Herman Jalli; Kissinger, Dietmar; Colantonio, Paolo
This paper presents a 4-way combined G-band power amplifier (PA) fabricated with a 130-nm SiGe BiCMOS process. First, a single-ended PA based on the cascode topology (CT) is designed at 185 GHz, which consists of three stages to get an overall gain and an output power higher than 27 dB and 13 dBm, respectively. Then, a 4-way combiner/splitter was designed using low-loss transmission lines at 130-210 GHz. Finally, the combiner was loaded with four single-ended PAs to complete the design of a 4-way combined PA. The chip of the fabricated PA occupies an area of 1.35mm2. The realized PA shows a saturated output power of 18.1 dBm with a peak gain of 25.9 dB and power-added efficiency (PAE) of 3.5% at 185 GHz. A maximum output power of 18.7 dBm with PAE of 4.4% is achieved at 170 GHz. The 3-dB and 6-dB bandwidth of the PA are 27 and 42 GHz, respectively. In addition, the PA delivers a saturated output power higher than 18 dBm in the frequency range 140-186 GHz. To the best of our knowledge, the power reported in this paper is the highest for G-band SiGe BiCMOS PAs. © 2013 IEEE.
The 16th Data Release of the Sloan Digital Sky Surveys: First Release from the APOGEE-2 Southern Survey and Full Release of eBOSS Spectra
(London : Institute of Physics Publ., 2020) Ahumada, Romina; Prieto, Carlos Allende; Almeida, Andrés; Anders, Friedrich; Anderson, Scott F.; Andrews, Brett H.; Anguiano, Borja; Arcodia, Riccardo; Armengaud, Eric; Aubert, Marie; Avila, Santiago; Garcia, Rafael A.; García-Hernández, D.A.; Oehmichen, Luis Alberto Garma; Ge, Junqiang; Maia, Marcio Antonio Geimba; Geisler, Doug; Gelfand, Joseph; Goddy, Julian; Gonzalez-Perez, Violeta; Grabowski, Kathleen; Avila-Reese, Vladimir; Green, Paul; Grier, Catherine J.; Guo, Hong; Guy, Julien; Harding, Paul; Hasselquist, Sten; Hawken, Adam James; Hayes, Christian R.; Hearty, Fred; Hekker, S.; Badenes, Carles; Hogg, David W.; Holtzman, Jon A.; Horta, Danny; Hou, Jiamin; Hsieh, Bau-Ching; Huber, Daniel; Hunt, Jason A. S.; Chitham, J. Ider; Imig, Julie; Jaber, Mariana; Balland, Christophe; Angel, Camilo Eduardo Jimenez; Johnson, Jennifer A.; Jones, Amy M.; Jönsson, Henrik; Jullo, Eric; Kim, Yerim; Kinemuchi, Karen; Kirkpatrick IV, Charles C.; Kite, George W.; Klaene, Mark; Barger, Kat; Kneib, Jean-Paul; Kollmeier, Juna A.; Kong, Hui; Kounkel, Marina; Krishnarao, Dhanesh; Lacerna, Ivan; Lan, Ting-Wen; Lane, Richard R.; Law, David R.; Le Goff, Jean-Marc; Barrera-Ballesteros, Jorge K.; Leung, Henry W.; Lewis, Hannah; Li, Cheng; Lian, Jianhui; Lin, Lihwai; Long, Dan; Longa-Peña, Penélope; Lundgren, Britt; Lyke, Brad W.; Ted Mackereth, J.; Basu, Sarbani; MacLeod, Chelsea L.; Majewski, Steven R.; Manchado, Arturo; Maraston, Claudia; Martini, Paul; Masseron, Thomas; Masters, Karen L.; Mathur, Savita; McDermid, Richard M.; Merloni, Andrea; Bautista, Julian; Merrifield, Michael; Mészáros, Szabolcs; Miglio, Andrea; Minniti, Dante; Minsley, Rebecca; Miyaji, Takamitsu; Mohammad, Faizan Gohar; Mosser, Benoit; Mueller, Eva-Maria; Muna, Demitri; Beaton, Rachael L.; Muñoz-Gutiérrez, Andrea; Myers, Adam D.; Nadathur, Seshadri; Nair, Preethi; Nandra, Kirpal; do Nascimento, Janaina Correa; Nevin, Rebecca Jean; Newman, Jeffrey A.; Nidever, David L.; Nitschelm, Christian; Beers, Timothy C.; Noterdaeme, Pasquier; O’Connell, Julia E.; Olmstead, Matthew D.; Oravetz, Daniel; Oravetz, Audrey; Osorio, Yeisson; Pace, Zachary J.; Padilla, Nelson; Palanque-Delabrouille, Nathalie; Palicio, Pedro A.; Benavides, B. Izamar T.; Pan, Hsi-An; Pan, Kaike; Parker, James; Paviot, Romain; Peirani, Sebastien; Ramŕez, Karla Peña; Penny, Samantha; Percival, Will J.; Perez-Fournon, Ismael; Pérez-Ràfols, Ignasi; Bender, Chad F.; Petitjean, Patrick; Pieri, Matthew M.; Pinsonneault, Marc; Poovelil, Vijith Jacob; Povick, Joshua Tyler; Prakash, Abhishek; Price-Whelan, Adrian M.; Raddick, M. Jordan; Raichoor, Anand; Ray, Amy; Bernardi, Mariangela; Rembold, Sandro Barboza; Rezaie, Mehdi; Riffel, Rogemar A.; Riffel, Rogério; Rix, Hans-Walter; Robin, Annie C.; Roman-Lopes, A.; Román-Zúñiga, Carlos; Rose, Benjamin; Ross, Ashley J.; Bershady, Matthew; Rossi, Graziano; Rowlands, Kate; Rubin, Kate H. R.; Salvato, Mara; Sánchez, Ariel G.; Sánchez-Menguiano, Laura; Sánchez-Gallego, José R.; Sayres, Conor; Schaefer, Adam; Schiavon, Ricardo P.; Beutler, Florian; Schimoia, Jaderson S.; Schlafly, Edward; Schlegel, David; Schneider, Donald P.; Schultheis, Mathias; Schwope, Axel; Seo, Hee-Jong; Serenelli, Aldo; Shafieloo, Arman; Shamsi, Shoaib Jamal; Bidin, Christian Moni; Shao, Zhengyi; Shen, Shiyin; Shetrone, Matthew; Shirley, Raphael; Aguirre, Víctor Silva; Simon, Joshua D.; Skrutskie, M.F.; Slosar, Anže; Smethurst, Rebecca; Sobeck, Jennifer; Bird, Jonathan; Sodi, Bernardo Cervantes; Souto, Diogo; Stark, David V.; Stassun, Keivan G.; Steinmetz, Matthias; Stello, Dennis; Stermer, Julianna; Storchi-Bergmann, Thaisa; Streblyanska, Alina; Stringfellow, Guy S.; Bizyaev, Dmitry; Stutz, Amelia; Suárez, Genaro; Sun, Jing; Taghizadeh-Popp, Manuchehr; Talbot, Michael S.; Tayar, Jamie; Thakar, Aniruddha R.; Theriault, Riley; Thomas, Daniel; Thomas, Zak C.; Blanc, Guillermo A.; Tinker, Jeremy; Tojeiro, Rita; Toledo, Hector Hernandez; Tremonti, Christy A.; Troup, Nicholas W.; Tuttle, Sarah; Unda-Sanzana, Eduardo; Valentini, Marica; Vargas-González, Jaime; Vargas-Magaña, Mariana; Blanton, Michael R.; Vázquez-Mata, Jose Antonio; Vivek, M.; Wake, David; Wang, Yuting; Weaver, Benjamin Alan; Weijmans, Anne-Marie; Wild, Vivienne; Wilson, John C.; Wilson, Robert F.; Wolthuis, Nathan; Boquien, Médéric; Wood-Vasey, W. M.; Yan, Renbin; Yang, Meng; Yèche, Christophe; Zamora, Olga; Zarrouk, Pauline; Zasowski, Gail; Zhang, Kai; Zhao, Cheng; Zhao, Gongbo; Borissova, Jura; Zheng, Zheng; Zheng, Zheng; Zhu, Guangtun; Zou, Hu; Bovy, Jo; Brandt, W. N.; Brinkmann, Jonathan; Brownstein, Joel R.; Bundy, Kevin; Bureau, Martin; Burgasser, Adam; Burtin, Etienne; Cano-Díaz, Mariana; Capasso, Raffaella; Cappellari, Michele; Carrera, Ricardo; Chabanier, Solène; Chaplin, William; Chapman, Michael; Cherinka, Brian; Chiappini, Cristina; Doohyun Choi, Peter; Chojnowski, S. Drew; Chung, Haeun; Clerc, Nicolas; Coffey, Damien; Comerford, Julia M.; Comparat, Johan; da Costa, Luiz; Cousinou, Marie-Claude; Covey, Kevin; Crane, Jeffrey D.; Cunha, Katia; Ilha, Gabriele da Silva; Dai, Yu Sophia; Damsted, Sanna B.; Darling, Jeremy; Davidson, James W.; Davies, Roger; Dawson, Kyle; De, Nikhil; de la Macorra, Axel; De Lee, Nathan; Queiroz, Anna Bárbara de Andrade; Deconto Machado, Alice; de la Torre, Sylvain; Dell’Agli, Flavia; du Mas des Bourboux, Hélion; Diamond-Stanic, Aleksandar M.; Dillon, Sean; Donor, John; Drory, Niv; Duckworth, Chris; Dwelly, Tom; Ebelke, Garrett; Eftekharzadeh, Sarah; Davis Eigenbrot, Arthur; Elsworth, Yvonne P.; Eracleous, Mike; Erfanianfar, Ghazaleh; Escoffier, Stephanie; Fan, Xiaohui; Farr, Emily; Fernández-Trincado, José G.; Feuillet, Diane; Finoguenov, Alexis; Fofie, Patricia; Fraser-McKelvie, Amelia; Frinchaboy, Peter M.; Fromenteau, Sebastien; Fu, Hai; Galbany, Lluís
This paper documents the 16th data release (DR16) from the Sloan Digital Sky Surveys (SDSS), the fourth and penultimate from the fourth phase (SDSS-IV). This is the first release of data from the Southern Hemisphere survey of the Apache Point Observatory Galactic Evolution Experiment 2 (APOGEE-2); new data from APOGEE-2 North are also included. DR16 is also notable as the final data release for the main cosmological program of the Extended Baryon Oscillation Spectroscopic Survey (eBOSS), and all raw and reduced spectra from that project are released here. DR16 also includes all the data from the Time Domain Spectroscopic Survey and new data from the SPectroscopic IDentification of ERosita Survey programs, both of which were co-observed on eBOSS plates. DR16 has no new data from the Mapping Nearby Galaxies at Apache Point Observatory (MaNGA) survey (or the MaNGA Stellar Library "MaStar"). We also preview future SDSS-V operations (due to start in 2020), and summarize plans for the final SDSS-IV data release (DR17).
19F NMR-, ESR-, and vis-NIR-spectroelectrochemical study of the unconventional reduction behaviour of a perfluoroalkylated fullerene: dimerization of the C70(CF3)10− radical anion
(Cambridge : Soc., 2015) Zalibera, Michal; Machata, Peter; Clikeman, Tyler T.; Rosenkranz, Marco; Strauss, Steven H.; Boltalina, Olga V.; Popov, Alexey A.
The most abundant isomer of C70(CF3)10 (70-10-1) is a rare example of a perfluoroalkylated fullerene exhibiting electrochemically irreversible reduction. We show that electrochemical reversibility at the first reduction step is achieved at scan rates higher than 500 V s−1. Applying ESR-, vis-NIR-, and 19F NMR-spectroelectrochemistry, as well as mass spectrometry and DFT calculations, we show that the (70-10-1)− radical monoanion is in equilibrium with a singly-bonded diamagnetic dimeric dianion. This study is the first example of 19F NMR spectroelectrochemistry, which promises to be an important method for the elucidation of redox mechanisms of fluoroorganic compounds. Additionally, we demonstrate the importance of combining different spectroelectrochemical methods and quantitative analysis of the transferred charge and spin numbers in the determination of the redox mechanism.

Browse

Browsing Fachgebiete by Title

Results Per Page

Sort Options