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Title: (+)-{1,2-Bis[(2R,5R)-2,5-diethyl-phospho-lan-1-yl]ethane- κ2 P,P′}(≠4-cyclo-octa-1,5-diene)rhodium(I) tetra-fluoridoborate
Authors: Schulz, S.Fischer, C.Drexler, H.-J.Heller, D.
Publishers version: https://doi.org/10.1107/S1600536810039577
URI: https://doi.org/10.34657/4044
https://oa.tib.eu/renate/handle/123456789/5415
Issue Date: 2010
Published in: Acta Crystallographica Section E: Structure Reports Online 66 (2010), 11
Publisher: Chester : International Union of Crystallography
Abstract: The title compound, [Rh(C8H12)(C18H 36P2)]BF4, exhibits a rhodium(I) complex cation with a bidentate bis-phosphine ligand and a bidentate 2, 2-coordinated cyclo-octa-1,5-diene ligand. The ligands form a slightly distorted square-planar coordination environment for the Rh(I) atom. An intra-molecular P-Rh-P bite angle of 83.91 (2)° is observed. The dihedral angle between the P - Rh - P and the X - Rh - X planes (X is the centroid of a double bond) is 14.0 (1)°. The BF4 anion is disordered over two positions in a 0.515 (7):0.485 (7) ratio.
Keywords: Crystal structure; Chemistry; Crystallography
Type: article; Text
Publishing status: publishedVersion
DDC: 540
License: CC BY 4.0 Unported
Link to license: https://creativecommons.org/licenses/by/4.0/
Appears in Collections:Chemie

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Schulz, S., C. Fischer, H.-J. Drexler and D. Heller, 2010. (+)-{1,2-Bis[(2R,5R)-2,5-diethyl-phospho-lan-1-yl]ethane- κ2 P,P′}(≠4-cyclo-octa-1,5-diene)rhodium(I) tetra-fluoridoborate. 2010. Chester : International Union of Crystallography
Schulz, S., Fischer, C., Drexler, H.-J. and Heller, D. (2010) “(+)-{1,2-Bis[(2R,5R)-2,5-diethyl-phospho-lan-1-yl]ethane- κ2 P,P′}(≠4-cyclo-octa-1,5-diene)rhodium(I) tetra-fluoridoborate.” Chester : International Union of Crystallography. doi: https://doi.org/10.1107/S1600536810039577.
Schulz S, Fischer C, Drexler H-J, Heller D. (+)-{1,2-Bis[(2R,5R)-2,5-diethyl-phospho-lan-1-yl]ethane- κ2 P,P′}(≠4-cyclo-octa-1,5-diene)rhodium(I) tetra-fluoridoborate. Vol. 66. Chester : International Union of Crystallography; 2010.
Schulz, S., Fischer, C., Drexler, H.-J., & Heller, D. (2010). (+)-{1,2-Bis[(2R,5R)-2,5-diethyl-phospho-lan-1-yl]ethane- κ2 P,P′}(≠4-cyclo-octa-1,5-diene)rhodium(I) tetra-fluoridoborate (Version publishedVersion, Vol. 66). Version publishedVersion, Vol. 66. Chester : International Union of Crystallography. https://doi.org/https://doi.org/10.1107/S1600536810039577
Schulz S, Fischer C, Drexler H-J, Heller D. (+)-{1,2-Bis[(2R,5R)-2,5-diethyl-phospho-lan-1-yl]ethane- κ2 P,P′}(≠4-cyclo-octa-1,5-diene)rhodium(I) tetra-fluoridoborate. 2010;66(11). doi:https://doi.org/10.1107/S1600536810039577


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