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Title: (+)-{1,2-Bis[(2R,5R)-2,5-dimethyl-phospho-lan-1-yl]ethane- κ2 P,P′}(η4-cyclo-octa-1,5-diene) rhodium(I) tetra-fluorido-borate
Authors: Schulz, S.Drexler, H.-J.Heller, D.
Publishers version: https://doi.org/10.1107/S1600536810019859
URI: https://doi.org/10.34657/4045
https://oa.tib.eu/renate/handle/123456789/5416
Issue Date: 2010
Published in: Acta Crystallographica Section E: Structure Reports Online 66 (2010), 6
Publisher: Chester : International Union of Crystallography
Abstract: The title compound, [Rh(C8H12)(C14H 28P2)]BF4, exhibits a rhodium(I) complex cation with a bidentate bis-phosphine ligand and a bidentate η2, η2-coordinated cyclo-octa-1,5-diene. Together the ligands create a slightly distorted square-planar cordination environment for the Rh(I) atom. There are three mol-ecules in the asymmetric unit and intra-molecular P - Rh - P bite angles of 82.78 (5), 82.97 (6) and 83.09 (5)° are observed. The dihedral angles between the P - Rh - P and the X - Rh - X planes (X is the centroid of a double bond) are 14.7 (1), 14.8 (1) and 15.3 (1)°. The structure exhibits disorder of one cyclo-octa-diene ligand as well as one BF4 anion.
Keywords: Crystal structure; Chemistry; Crystallography
Type: article; Text
Publishing status: publishedVersion
DDC: 540
License: CC BY 4.0 Unported
Link to license: https://creativecommons.org/licenses/by/4.0/
Appears in Collections:Chemie

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Schulz, S., H.-J. Drexler and D. Heller, 2010. (+)-{1,2-Bis[(2R,5R)-2,5-dimethyl-phospho-lan-1-yl]ethane- κ2 P,P′}(η4-cyclo-octa-1,5-diene) rhodium(I) tetra-fluorido-borate. 2010. Chester : International Union of Crystallography
Schulz, S., Drexler, H.-J. and Heller, D. (2010) “(+)-{1,2-Bis[(2R,5R)-2,5-dimethyl-phospho-lan-1-yl]ethane- κ2 P,P′}(η4-cyclo-octa-1,5-diene) rhodium(I) tetra-fluorido-borate.” Chester : International Union of Crystallography. doi: https://doi.org/10.1107/S1600536810019859.
Schulz S, Drexler H-J, Heller D. (+)-{1,2-Bis[(2R,5R)-2,5-dimethyl-phospho-lan-1-yl]ethane- κ2 P,P′}(η4-cyclo-octa-1,5-diene) rhodium(I) tetra-fluorido-borate. Vol. 66. Chester : International Union of Crystallography; 2010.
Schulz, S., Drexler, H.-J., & Heller, D. (2010). (+)-{1,2-Bis[(2R,5R)-2,5-dimethyl-phospho-lan-1-yl]ethane- κ2 P,P′}(η4-cyclo-octa-1,5-diene) rhodium(I) tetra-fluorido-borate (Version publishedVersion, Vol. 66). Version publishedVersion, Vol. 66. Chester : International Union of Crystallography. https://doi.org/https://doi.org/10.1107/S1600536810019859
Schulz S, Drexler H-J, Heller D. (+)-{1,2-Bis[(2R,5R)-2,5-dimethyl-phospho-lan-1-yl]ethane- κ2 P,P′}(η4-cyclo-octa-1,5-diene) rhodium(I) tetra-fluorido-borate. 2010;66(6). doi:https://doi.org/10.1107/S1600536810019859


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