(tert-Butylimido)bis(η5-cyclopenta-dienyl) pyridinezirconium(IV)

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Date
2010
Journal Title
Journal ISSN
Volume Title
Publisher
Chester : International Union of Crystallography
Abstract

The title compound, [Zr(C5H5)2(C 4H9N)(C5H5N)], was obtained from the reaction of (C5H5)2Zr(py)(η2- Me3SiC2SiMe3) (py is pyridine) and tBuN=C=NtBu alongside the formation of (C 5H5)2Zr(CNtBu)(2-Me 3SiC2SiMe3). The zirconium atom is coordinated in a distorted tetrahedral geometry by two cyclopentadienyl ligands, a pyridine ligand, and a tertbutylimido ligand via a Zr=N double bond. The tertbutyl group is disordered over two positions in a 0.634 (5):0.366 (5) ratio.

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Keywords
Crystal structure, Chemistry, Crystallography
Citation
Citation
Kaleta, K., Arndt, P., Spannenberg, A., & Rosenthal, U. (2010). (tert-Butylimido)bis(η5-cyclopenta-dienyl) pyridinezirconium(IV) (Version publishedVersion, Vol. 66). Version publishedVersion, Vol. 66. Chester : International Union of Crystallography. https://doi.org//10.1107/S1600536810033556
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