[Bis(diphenylphosphanyl)dimethylsilane κ2P,P′] tetracarbonylchromium(0)

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Date
2010
Volume
66
Issue
11
Journal
Acta Crystallographica Section E: Structure Reports Online
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Book Title
Publisher
Chester : International Union of Crystallography
Abstract

The title compound, [Cr(C26H26P2Si)(CO) 4], was obtained by the reaction of Ph2PSiMe 2PPh2 with Cr(CO)6 in refluxing toluene by ligand exchange. The CrC4P2 coordination geometry at the Cr atom is distorted octa-hedral, with a P - Cr - P bite angle of 80.27 (1)°.

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Citation
Peulecke, N., Peitz, S., Müller, B. H., Spannenberg, A., & Rosenthal, U. (2010). [Bis(diphenylphosphanyl)dimethylsilane κ2P,P′] tetracarbonylchromium(0) (Chester : International Union of Crystallography). Chester : International Union of Crystallography. https://doi.org//10.1107/S1600536810043679
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CC BY 4.0 Unported