Bis(dimethyl sulfoxide)hydridobis(triphenylphosphane)cobalt(I)
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Date
2010
Authors
Volume
66
Issue
8
Journal
Acta Crystallographica Section E: Structure Reports Online
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Book Title
Publisher
Chester : International Union of Crystallography
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Abstract
The title compound, [CoH(C18H15P)2(C 2H6OS)2], was synthesized by the reaction of chloridotris(triphenyl-phosphane)cobalt(I), [ClCo(PPh3)3], in the presence of one equivalent potassium hydridotris(pyrazol-yl)borate in dimethyl sulfoxide. The structure displays a distorted trigonal-pyramidally coordinated cobalt(I) atom, with two phosphane ligands and one DMSO ligand in the equatorial plane. The coordination is completed by one further DMSO ligand and the anionic hydride in the axial positions.
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Citation
Hapke, M., Weding, N., & Spannenberg, A. (2010). Bis(dimethyl sulfoxide)hydridobis(triphenylphosphane)cobalt(I) (Chester : International Union of Crystallography). Chester : International Union of Crystallography. https://doi.org//10.1107/S1600536810029466
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CC BY 4.0 Unported