(Cyanido-κC)(2,2-diphenylacetamido-κ2 N,O)bis(η5-pentamethylcyclopentadienyl)zirconium(IV)

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Date
2014
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Volume Title
Publisher
Chester : International Union of Crystallography
Abstract

In the title compound, [Zr(C10H15)2(C14H12NO)(CN)], the ZrIV atom is coordinated by two pentamethylcyclopentadienyl ligands, the amidate ligand via the N and O atoms, and an additional C N ligand. The four-membered metallacycle is nearly planar (r.m.s. deviation = 0.008Å). In the crystal, the molecules are connected into centrosymmetric dimers via pairs of N - HN hydrogen bonds.

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Keywords
data-to-parameter ratio = 17.9, mean σ(C-C) = 0.003 Å, R factor = 0.033, single-crystal X-ray study, T = 150 K, wR factor = 0.085
Citation
Citation
Becker, L., Spannenberg, A., Arndt, P., & Rosenthal, U. (2014). (Cyanido-κC)(2,2-diphenylacetamido-κ2 N,O)bis(η5-pentamethylcyclopentadienyl)zirconium(IV) (Version publishedVersion, Vol. 70). Version publishedVersion, Vol. 70. Chester : International Union of Crystallography. https://doi.org//10.1107/S1600536814001160
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