Bis(μ2-isopropylimido-κ2 N:N)bis[(η5-cyclopentadienyl)(ethenolato-κO)titanium(IV)]
Loading...
Date
2014
Authors
Journal Title
Journal ISSN
Volume Title
Publisher
Chester : International Union of Crystallography
Abstract
The title dinuclear half-sandwich complex, [CpTi(OCH=CH2) (μ2-N-iPr)]2 (Cp = cyclopentadienyl; iPr = isopropyl), was obtained from the reaction of Cp2TiCl2, n-butyllithium and isopropylamine in tetrahydrofuran. Each TiIV atom is coordinated by one Cp ligand, one vinyloxy unit and two bridging imido groups in a strongly distorted tetrahedral geometry. There are two half molecules in the asymmetric unit, such that whole molecules being generated by inversion symmetry.
Description
Keywords
chemistry, crystal structures
Citation
Citation
Haehnel, M., Spannenberg, A., & Rosenthal, U. (2014). Bis(μ2-isopropylimido-κ2 N:N)bis[(η5-cyclopentadienyl)(ethenolato-κO)titanium(IV)] (Version publishedVersion, Vol. 70). Version publishedVersion, Vol. 70. Chester : International Union of Crystallography. https://doi.org//10.1107/S1600536813033072