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| Title: | (+)-Chlorido[(1,2,3,4-η;P 2′)-2′- diphenylphosphanyl-2-diphenylphosphoryl-1,1′-binaphthyl]rhodium(I) methanol monosolvate |
| Authors: | Meissner, A.; Selle, C.; Drexler, H.-J.; Heller, D. |
| Publishers version: | https://doi.org/10.1107/S1600536812003418 |
| URI: | https://doi.org/10.34657/4203 https://oa.tib.eu/renate/handle/123456789/5574 |
| Issue Date: | 2012 |
| Published in: | Acta Crystallographica Section E: Structure Reports Online 68 (2012), 3 |
| Publisher: | Chester : International Union of Crystallography |
| Abstract: | In the title complex, [RhCl(C 44H 32OP 2)]·CH 3OH, the Rh I ion is coordinated by a naphthyl group of a partially oxidized 2,2′-bis-(diphenylphosphanyl)-1, 1′-binaphthyl (BINAP) ligand in a 4 mode, one P atom of the diphenylphosphanyl group and one Cl atom. The P=O group does not interact with the Rh I ion but accepts an O - H⋯O hydrogen bond from the methanol solvent molecule. |
| Keywords: | data-to-parameter ratio = 13.5; mean σ(C-C) = 0.006 Å; R factor = 0.027; single-crystal X-ray study; T = 200 K; wR factor = 0.043 |
| Type: | article; Text |
| Publishing status: | publishedVersion |
| DDC: | 540 |
| License: | CC BY 4.0 Unported |
| Link to license: | https://creativecommons.org/licenses/by/4.0/ |
| Appears in Collections: | Chemie |
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Meissner, A., C. Selle, H.-J. Drexler and D. Heller, 2012. (+)-Chlorido[(1,2,3,4-η;P 2′)-2′- diphenylphosphanyl-2-diphenylphosphoryl-1,1′-binaphthyl]rhodium(I) methanol monosolvate. 2012. Chester : International Union of Crystallography
Meissner, A., Selle, C., Drexler, H.-J. and Heller, D. (2012) “(+)-Chlorido[(1,2,3,4-η;P 2′)-2′- diphenylphosphanyl-2-diphenylphosphoryl-1,1′-binaphthyl]rhodium(I) methanol monosolvate.” Chester : International Union of Crystallography. doi: https://doi.org/10.1107/S1600536812003418.
Meissner A, Selle C, Drexler H-J, Heller D. (+)-Chlorido[(1,2,3,4-η;P 2′)-2′- diphenylphosphanyl-2-diphenylphosphoryl-1,1′-binaphthyl]rhodium(I) methanol monosolvate. Vol. 68. Chester : International Union of Crystallography; 2012.
Meissner, A., Selle, C., Drexler, H.-J., & Heller, D. (2012). (+)-Chlorido[(1,2,3,4-η;P 2′)-2′- diphenylphosphanyl-2-diphenylphosphoryl-1,1′-binaphthyl]rhodium(I) methanol monosolvate (Version publishedVersion, Vol. 68). Version publishedVersion, Vol. 68. Chester : International Union of Crystallography. https://doi.org/https://doi.org/10.1107/S1600536812003418
Meissner A, Selle C, Drexler H-J, Heller D. (+)-Chlorido[(1,2,3,4-η;P 2′)-2′- diphenylphosphanyl-2-diphenylphosphoryl-1,1′-binaphthyl]rhodium(I) methanol monosolvate. 2012;68(3). doi:https://doi.org/10.1107/S1600536812003418
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