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Title: (+)-Chlorido[(1,2,3,4-η;P 2′)-2′- diphenylphosphanyl-2-diphenylphosphoryl-1,1′-binaphthyl]rhodium(I) methanol monosolvate
Authors: Meissner, A.Selle, C.Drexler, H.-J.Heller, D.
Publishers version: https://doi.org/10.1107/S1600536812003418
URI: https://doi.org/10.34657/4203
https://oa.tib.eu/renate/handle/123456789/5574
Issue Date: 2012
Published in: Acta Crystallographica Section E: Structure Reports Online 68 (2012), 3
Publisher: Chester : International Union of Crystallography
Abstract: In the title complex, [RhCl(C 44H 32OP 2)]·CH 3OH, the Rh I ion is coordinated by a naphthyl group of a partially oxidized 2,2′-bis-(diphenylphosphanyl)-1, 1′-binaphthyl (BINAP) ligand in a 4 mode, one P atom of the diphenylphosphanyl group and one Cl atom. The P=O group does not interact with the Rh I ion but accepts an O - H⋯O hydrogen bond from the methanol solvent molecule.
Keywords: data-to-parameter ratio = 13.5; mean σ(C-C) = 0.006 Å; R factor = 0.027; single-crystal X-ray study; T = 200 K; wR factor = 0.043
Type: article; Text
Publishing status: publishedVersion
DDC: 540
License: CC BY 4.0 Unported
Link to license: https://creativecommons.org/licenses/by/4.0/
Appears in Collections:Chemie

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Meissner, A., C. Selle, H.-J. Drexler and D. Heller, 2012. (+)-Chlorido[(1,2,3,4-η;P 2′)-2′- diphenylphosphanyl-2-diphenylphosphoryl-1,1′-binaphthyl]rhodium(I) methanol monosolvate. 2012. Chester : International Union of Crystallography
Meissner, A., Selle, C., Drexler, H.-J. and Heller, D. (2012) “(+)-Chlorido[(1,2,3,4-η;P 2′)-2′- diphenylphosphanyl-2-diphenylphosphoryl-1,1′-binaphthyl]rhodium(I) methanol monosolvate.” Chester : International Union of Crystallography. doi: https://doi.org/10.1107/S1600536812003418.
Meissner A, Selle C, Drexler H-J, Heller D. (+)-Chlorido[(1,2,3,4-η;P 2′)-2′- diphenylphosphanyl-2-diphenylphosphoryl-1,1′-binaphthyl]rhodium(I) methanol monosolvate. Vol. 68. Chester : International Union of Crystallography; 2012.
Meissner, A., Selle, C., Drexler, H.-J., & Heller, D. (2012). (+)-Chlorido[(1,2,3,4-η;P 2′)-2′- diphenylphosphanyl-2-diphenylphosphoryl-1,1′-binaphthyl]rhodium(I) methanol monosolvate (Version publishedVersion, Vol. 68). Version publishedVersion, Vol. 68. Chester : International Union of Crystallography. https://doi.org/https://doi.org/10.1107/S1600536812003418
Meissner A, Selle C, Drexler H-J, Heller D. (+)-Chlorido[(1,2,3,4-η;P 2′)-2′- diphenylphosphanyl-2-diphenylphosphoryl-1,1′-binaphthyl]rhodium(I) methanol monosolvate. 2012;68(3). doi:https://doi.org/10.1107/S1600536812003418


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