(+)-Chlorido[(1,2,3,4-η;P 2′)-2′- diphenylphosphanyl-2-diphenylphosphoryl-1,1′-binaphthyl]rhodium(I) methanol monosolvate

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Date
2012
Volume
68
Issue
3
Journal
Series Titel
Book Title
Publisher
Chester : International Union of Crystallography
Abstract

In the title complex, [RhCl(C 44H 32OP 2)]·CH 3OH, the Rh I ion is coordinated by a naphthyl group of a partially oxidized 2,2′-bis-(diphenylphosphanyl)-1, 1′-binaphthyl (BINAP) ligand in a 4 mode, one P atom of the diphenylphosphanyl group and one Cl atom. The P=O group does not interact with the Rh I ion but accepts an O - H⋯O hydrogen bond from the methanol solvent molecule.

Description
Keywords
data-to-parameter ratio = 13.5, mean σ(C-C) = 0.006 Å, R factor = 0.027, single-crystal X-ray study, T = 200 K, wR factor = 0.043
Citation
Meissner, A., Selle, C., Drexler, H.-J., & Heller, D. (2012). (+)-Chlorido[(1,2,3,4-η;P 2′)-2′- diphenylphosphanyl-2-diphenylphosphoryl-1,1′-binaphthyl]rhodium(I) methanol monosolvate. 68(3). https://doi.org//10.1107/S1600536812003418
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CC BY 4.0 Unported