Tetracarbonyl[bis(diphenylphosphanyl)-tetramethyldisiloxane- κ 2 P,P′]chromium(0)

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Date
2012
Volume
68
Issue
2
Journal
Acta Crystallographica Section E: Structure Reports Online
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Book Title
Publisher
Chester : International Union of Crystallography
Abstract

The title compound, [Cr(C 28H 32OP 2Si 2)(CO) 4], was obtained by the ligand-exchange reaction of Cr(CO) 6 with (Ph 2PSiMe 2) 2O in refluxing toluene. The CrC 4P 2 coordination geometry is distorted octa-hedral, with a P - Cr - P bite angle of 99.22 (4)°.

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Citation
Peulecke, N., Müller, B. H., Spannenberg, A., & Rosenthal, U. (2012). Tetracarbonyl[bis(diphenylphosphanyl)-tetramethyldisiloxane- κ 2 P,P′]chromium(0) (Chester : International Union of Crystallography). Chester : International Union of Crystallography. https://doi.org//10.1107/S1600536812000219
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CC BY 4.0 Unported