(μ3-Hydrido)[μ3-2-(trimethylsilyl) ethylidyne-κ3C1:C1:C1] tetrakis[(η5-cyclopentadienyl)cobalt(II)]
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Date
2013
Authors
Volume
69
Issue
12
Journal
Series Titel
Book Title
Publisher
Chester : International Union of Crystallography
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Abstract
In the title compound, [Co4(C5H5) 4(μ3-CCH2SiMe3)(μ3-H)], the Co atoms form a distorted tetrahedron with the ethylidyne moiety bridging three of the Co atoms as well as the hydrido ligand also bridging three of the Co atoms. The Co-Co bond lengths in the Co4tetrahedron vary from 2.3844 (4) to 2.4608 (4) Å. Each Co atom is additionally η5-bonded to a cyclopentadienyl (Cp) anion.
Description
Keywords
chemistry, crystal structures
Citation
Haehnel, M., Spannenberg, A., & Rosenthal, U. (2013). (μ3-Hydrido)[μ3-2-(trimethylsilyl) ethylidyne-κ3C1:C1:C1] tetrakis[(η5-cyclopentadienyl)cobalt(II)]. 69(12). https://doi.org//10.1107/S1600536813030432
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License
CC BY 4.0 Unported