Tetracarbonyl[N-(diphenylphosphanyl-κP)-N,N′-diisopropyl-P-phenylphosphorus diamide-κP]molybdenum(0) with an unknown solvent
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Date
2018
Journal Title
Journal ISSN
Volume Title
Publisher
Chester : IUCr
Abstract
The title complex, [Mo(C24H30N2P2)(CO)4], contains a molybdenum centre bearing a P,P′-cis-chelating Ph2PN(iPr)P(Ph)NH(iPr) and four carbonyl ligands in a distorted octahedral coordination geometry. This results in a nearly planar four-membered metallacycle. In the crystal, molecules are linked by N—H...O and C—H...O hydrogen bonds to form layers parallel to the ac plane. For the final refinement, the contributions of disordered solvent molecules were removed from the diffraction data with SQUEEZE in PLATON [Spek (2015). Acta Cryst. C71, 9–18]. The given chemical formula and other crystal data do not take into account the unknown solvent molecule(s).
Description
Keywords
crystal structure, molybdenum, diphosphazane
Citation
Citation
Höhne, M., Gongoll, M., Spannenberg, A., Müller, B. H., Peulecke, N., & Rosenthal, U. (2018). Tetracarbonyl[N-(diphenylphosphanyl-κP)-N,N′-diisopropyl-P-phenylphosphorus diamide-κP]molybdenum(0) with an unknown solvent (Version publishedVersion, Vol. 3). Version publishedVersion, Vol. 3. Chester : IUCr. https://doi.org//10.1107/S2414314618008465