Tetra­carbon­yl[N-(di­phenyl­phosphanyl-κP)-N,N′-diisoprop­yl-P-phenyl­phospho­rus di­amide-κP]molybdenum(0) with an unknown solvent

Loading...
Thumbnail Image
Date
2018
Volume
3
Issue
Journal
Series Titel
Book Title
Publisher
Chester : IUCr
Abstract

The title complex, [Mo(C24H30N2P2)(CO)4], contains a molybdenum centre bearing a P,P′-cis-chelating Ph2PN(iPr)P(Ph)NH(iPr) and four carbonyl ligands in a distorted octa­hedral coordination geometry. This results in a nearly planar four-membered metallacycle. In the crystal, mol­ecules are linked by N—H...O and C—H...O hydrogen bonds to form layers parallel to the ac plane. For the final refinement, the contributions of disordered solvent mol­ecules were removed from the diffraction data with SQUEEZE in PLATON [Spek (2015). Acta Cryst. C71, 9–18]. The given chemical formula and other crystal data do not take into account the unknown solvent mol­ecule(s).

Description
Keywords
crystal structure, molybdenum, diphosphazane
Citation
Höhne, M., Gongoll, M., Spannenberg, A., Müller, B. H., Peulecke, N., & Rosenthal, U. (2018). Tetra­carbon­yl[N-(di­phenyl­phosphanyl-κP)-N,N′-diisoprop­yl-P-phenyl­phospho­rus di­amide-κP]molybdenum(0) with an unknown solvent. 3. https://doi.org//10.1107/S2414314618008465
Collections
License
CC BY 4.0 Unported