Manganese-catalyzed selective C–H activation and deuteration by means of a catalytic transient directing group strategy
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Date
2021
Volume
57
Issue
9
Journal
Chemical Communications
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Publisher
London : Royal Society of Chemistry (RSC)
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Abstract
A novel manganese-catalyzed C-H activation methodology for selective hydrogen isotope exchange of benzaldehydes is presented. Using D2O as a cheap and convenient source of deuterium, the reaction proceeds with excellent functional group tolerance. Highortho-selectivity is achieved in the presence of catalytic amounts of specific amines, whichin situform a transient directing group. © The Royal Society of Chemistry 2021.
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Citation
Kopf, S., Neumann, H., & Beller, M. (2021). Manganese-catalyzed selective C–H activation and deuteration by means of a catalytic transient directing group strategy (London : Royal Society of Chemistry (RSC)). London : Royal Society of Chemistry (RSC). https://doi.org//10.1039/d0cc07675a
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CC BY-NC 3.0 Unported