Crystal structure of 1,1,2,2-tetramethyl-1,2-bis(2,3,4,5-tetramethylcyclopenta-2,4-dien-1-yl)disilane
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Date
2015
Journal Title
Journal ISSN
Volume Title
Publisher
Chester : International Union of Crystallography
Abstract
The molecular structure of the title compound, C22H38Si2, features a trans arrangement of the cyclopentadienyl rings to avoid steric strain [C-Si-Si-C torsion angle = -179.0 (5)°]. The Si-Si bond length is 2.3444 (4) Å. The most notable intermolecular interactions in the molecular packing are C-H...[pi] contacts that lead to the formation of wave-like supramolecular chains along the b axis.
Description
Keywords
ansa ligand, crystal structure, disilane
Citation
Citation
Godemann, C., Spannenberg, A., & Beweries, T. (2015). Crystal structure of 1,1,2,2-tetramethyl-1,2-bis(2,3,4,5-tetramethylcyclopenta-2,4-dien-1-yl)disilane (Version publishedVersion, Vol. E71). Version publishedVersion, Vol. E71. Chester : International Union of Crystallography. https://doi.org//10.1107/S2056989015019891