Crystal structure of (1S,2R,4S)-1-[(morpholin-4-yl)-methyl]-4-(prop-1-en-2-yl)cyclohexane-1,2-diol
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Date
2015
Volume
E71
Issue
1
Journal
Series Titel
Book Title
Publisher
Chester : International Union of Crystallography
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Abstract
The asymmetric unit of the title compound, C14H25NO3, contains two independent molecules with similar geometry. The morpholine and cyclohexane rings of both molecules adopt a chair conformation. Intramolecular O-H...N hydrogen bonds are observed. In the crystal, molecules are linked by O-H...O hydrogen bonds into chains parallel to the [101] direction. The chains are further connected through C-H...O hydrogen bonds forming undulating layers parallel to the (-101) plane. The absolute configuration was assigned by reference to an unchanging chiral centre in the synthetic procedure.
Description
Keywords
Amino-1,2-diol, Chiral ligand for catalytic enantioselective transformations, Crystal structure, Hydrogen bonds
Citation
Outouch, R., Oubaassine, S., Ali, M. A., El Firdoussi, L., & Spannenberg, A. (2015). Crystal structure of (1S,2R,4S)-1-[(morpholin-4-yl)-methyl]-4-(prop-1-en-2-yl)cyclohexane-1,2-diol. E71(1). https://doi.org//10.1107/S2056989014027169
License
CC BY 2.0 UK