Modified bibenzimidazole ligands as spectator ligands in photoactive molecular functional Ru-polypyridine units? Implications from spectroscopy

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dc.bibliographicCitation.firstPage17659eng
dc.bibliographicCitation.issue47eng
dc.bibliographicCitation.journalTitleDalton Transactionseng
dc.bibliographicCitation.volume43eng
dc.contributor.authorMeyer-Ilse, J.
dc.contributor.authorBauroth, S.
dc.contributor.authorBräutigam, M.
dc.contributor.authorSchmitt, M.
dc.contributor.authorPopp, J.
dc.contributor.authorBeckert, R.
dc.contributor.authorRockstroh, N.
dc.contributor.authorPilz, T.D.
dc.contributor.authorMonczak, K.
dc.contributor.authorHeinemann, F.W.
dc.contributor.authorRau, S.
dc.contributor.authorDietzek, B.
dc.date.accessioned2020-09-25T12:04:51Z
dc.date.available2020-09-25T12:04:51Z
dc.date.issued2014
dc.description.abstractThe photophysical properties of Ruthenium-bipyridine complexes bearing a bibenzimidazole ligand were investigated. The nitrogens on the bibenzimidazole-ligand were protected, by adding either a phenylene group or a 1,2-ethandiyl group, to remove the photophysical dependence of the complex on the protonation state of the bibenzimidazole ligand. This protection results in the bibenzimidazole ligand contributing to the MLCT transition, which is experimentally evidenced by (resonance) Raman scattering in concert with DFT calculations for a detailed mode assignment in the (resonance) Raman spectra.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://doi.org/10.34657/4304
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/5675
dc.language.isoengeng
dc.publisherCambridge : RSCeng
dc.relation.doihttps://doi.org/10.1039/c4dt01399a
dc.relation.issn1477-9226
dc.rights.licenseCC BY 3.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by/3.0/eng
dc.subject.ddc540eng
dc.subject.otherRaman scatteringeng
dc.subject.otherRuthenium compoundseng
dc.subject.otherDFT calculationeng
dc.subject.otherMode-assignmenteng
dc.subject.otherPhenylene groupseng
dc.subject.otherPhotophysical propertieseng
dc.subject.otherPolypyridineseng
dc.subject.otherProtonation stateeng
dc.subject.otherRuthenium-bipyridine complexeseng
dc.subject.otherSpectator ligandseng
dc.subject.otherLigandseng
dc.subject.otherbenzimidazoleeng
dc.subject.otherbenzimidazole derivativeeng
dc.subject.otherligandeng
dc.subject.otherorganometallic compoundeng
dc.subject.otherpyridine derivativeeng
dc.subject.otherrutheniumeng
dc.subject.otherchemistryeng
dc.subject.otherphotochemistryeng
dc.subject.otherquantum theoryeng
dc.subject.otherRaman spectrometryeng
dc.subject.othersynthesiseng
dc.subject.otherBenzimidazoleseng
dc.subject.otherLigandseng
dc.subject.otherOrganometallic Compoundseng
dc.subject.otherPhotochemical Processeseng
dc.subject.otherPyridineseng
dc.subject.otherQuantum Theoryeng
dc.subject.otherRutheniumeng
dc.subject.otherSpectrum Analysis, Ramaneng
dc.titleModified bibenzimidazole ligands as spectator ligands in photoactive molecular functional Ru-polypyridine units? Implications from spectroscopyeng
dc.typeArticleeng
dc.typeTexteng
tib.accessRightsopenAccesseng
wgl.contributorIPHTeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
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