Self-assembly of gold nanoparticles at the oil-vapor interface: from mono- to multilayers

dc.bibliographicCitation.firstPage13176
dc.bibliographicCitation.issue44eng
dc.bibliographicCitation.journalTitleLangmuireng
dc.bibliographicCitation.lastPage13181
dc.bibliographicCitation.volume30
dc.contributor.authorBorn, Philip
dc.contributor.authorSchön, Volker
dc.contributor.authorBlum, Susanne
dc.contributor.authorGerstner, Dominik
dc.contributor.authorHuber, Patrick
dc.contributor.authorKraus, Tobias
dc.date.accessioned2016-03-24T17:36:56Z
dc.date.available2019-06-28T12:39:13Z
dc.date.issued2014
dc.description.abstractAlkylthiol-coated gold nanoparticles spontaneously segregate from dispersion in toluene to the toluene-vapor interface. We show that surface tension drops during segregation with a rate that depends on particle concentration. Mono- and multilayers of particles form depending on particle concentration, time, and temperature. X-ray reflectometry indicates fast monolayer formation and slow multilayer formation. A model that combines diffusion-limited segregation driven by surface energy and heterogeneous agglomeration driven by dispersive van der Waals particle interactions is proposed to describe film formation.
dc.description.versionpublishedVersioneng
dc.formatapplication/pdf
dc.identifier.urihttps://doi.org/10.34657/1645
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/4219
dc.language.isoengeng
dc.publisherWashington D.C. : American Chemical Society
dc.relation.doihttps://doi.org/10.1021/la503551d
dc.rights.licenseDieses Dokument darf im Rahmen von § 53 UrhG zum eigenen Gebrauch kostenfrei heruntergeladen, gelesen, gespeichert und ausgedruckt, aber nicht im Internet bereitgestellt oder an Außenstehende weitergegeben werden.ger
dc.rights.licenseThis document may be downloaded, read, stored and printed for your own use within the limits of § 53 UrhG but it may not be distributed via the internet or passed on to external parties.eng
dc.subject.ddc530
dc.titleSelf-assembly of gold nanoparticles at the oil-vapor interface: from mono- to multilayers
dc.typeArticleeng
dc.typeTexteng
tib.accessRightsopenAccesseng
wgl.contributorINMeng
wgl.subjectPhysikeng
wgl.typeZeitschriftenartikeleng
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