2-Vinyl-pyridine-tris-(penta-fluoro-phen-yl)borane hexane monosolvate
| dc.bibliographicCitation.issue | 4 | |
| dc.bibliographicCitation.volume | 68 | eng |
| dc.contributor.author | Klahn, M. | |
| dc.contributor.author | Spannenberg, A. | |
| dc.contributor.author | Rosenthal, U. | |
| dc.date.accessioned | 2020-09-06T07:58:37Z | |
| dc.date.available | 2020-09-06T07:58:37Z | |
| dc.date.issued | 2012 | |
| dc.description.abstract | The title compound, C7H7N·B(C 6F5)3·C6H14, was obtained by the stoichiometric reaction of 2-vinyl-pyridine and tris-(penta-fluoro-phen-yl) borane in toluene. The formed adduct exhibits a restricted rotation along the B-N bond resulting in an asymmetry, which can be also observed in the 19F NMR spectra. The B-N distance is equivalent to the distances found for 2-methyl-pyridine and 2-ethyl-pyridine B(C6F5)3 adducts. For the final refinement, the contributions of disordered solvent mol-ecules were removed from the diffraction data with SQUEEZE in PLATON [van der Sluis & Spek (1990). Acta Cryst. A46, 194-201; Spek (2009). Acta Cryst. D65, 148-155]. | eng |
| dc.description.version | publishedVersion | eng |
| dc.identifier.uri | https://doi.org/10.34657/4205 | |
| dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/5576 | |
| dc.language.iso | eng | eng |
| dc.publisher | Chester : International Union of Crystallography | eng |
| dc.relation.doi | https://doi.org/10.1107/S1600536812013153 | |
| dc.relation.ispartofseries | Acta Crystallographica Section E: Structure Reports Online 68 (2012), 4 | eng |
| dc.relation.issn | 1600-5368 | |
| dc.rights.license | CC BY 4.0 Unported | eng |
| dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | eng |
| dc.subject | chemistry | eng |
| dc.subject | crystal structures | eng |
| dc.subject.ddc | 540 | eng |
| dc.title | 2-Vinyl-pyridine-tris-(penta-fluoro-phen-yl)borane hexane monosolvate | eng |
| dc.type | article | eng |
| dc.type | Text | eng |
| dcterms.bibliographicCitation.journalTitle | Acta Crystallographica Section E: Structure Reports Online | eng |
| local.doifilter.override | ja | |
| tib.accessRights | openAccess | eng |
| wgl.contributor | LIKAT | eng |
| wgl.subject | Chemie | eng |
| wgl.type | Zeitschriftenartikel | eng |