(BB)-Carboryne Complex of Ruthenium: Synthesis by Double B-H Activation at a Single Metal Center

Simple item page
dc.bibliographicCitation.firstPage10531eng
dc.bibliographicCitation.issue33eng
dc.bibliographicCitation.journalTitleJournal of the American Chemical Societyeng
dc.bibliographicCitation.lastPage10538eng
dc.bibliographicCitation.volume138eng
dc.contributor.authorEleazer, Bennett J.
dc.contributor.authorSmith, Mark D.
dc.contributor.authorPopov, Alexey A.
dc.contributor.authorPeryshkov, Dmitry V.
dc.date.accessioned2022-05-18T06:29:20Z
dc.date.available2022-05-18T06:29:20Z
dc.date.issued2016
dc.description.abstractThe first example of a transition metal (BB)-carboryne complex containing two boron atoms of the icosahedral cage connected to a single exohedral metal center (POBBOP)Ru(CO)2 (POBBOP = 1,7-OP(i-Pr)2-2,6-dehydro-m-carborane) was synthesized by double B-H activation within the strained m-carboranyl pincer framework. Theoretical calculations revealed that the unique three-membered (BB)>Ru metalacycle is formed by two bent B-Ru σ-bonds with the concomitant increase of the bond order between the two metalated boron atoms. The reactivity of the highly strained electron-rich (BB)-carboryne fragment with small molecules was probed by reactions with electrophiles. The carboryne-carboranyl transformations reported herein represent a new mode of cooperative metal-ligand reactivity of boron-based complexes.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/8996
dc.identifier.urihttps://doi.org/10.34657/8034
dc.language.isoengeng
dc.publisherWashington, DC : ACS Publicationseng
dc.relation.doihttps://doi.org/10.1021/jacs.6b05172
dc.relation.essn1520-5126
dc.rights.licenseACS AuthorChoiceeng
dc.rights.urihttps://pubs.acs.org/page/policy/authorchoice_termsofuse.html
dc.subject.ddc540eng
dc.subject.otherBoroneng
dc.subject.otherChemical activationeng
dc.subject.otherMetalseng
dc.subject.otherPraseodymiumeng
dc.subject.otherRuthenium compoundseng
dc.subject.otherTransition metalseng
dc.subject.otherBond orderingeng
dc.subject.otherElectron-richeng
dc.subject.otherElectrophileseng
dc.subject.otherHighly strainedeng
dc.subject.otherMetal centerseng
dc.subject.otherMetal ligandseng
dc.subject.otherSmall moleculeseng
dc.subject.otherTheoretical calculationseng
dc.subject.otherRutheniumeng
dc.subject.otherboroneng
dc.subject.othercarboryne complexeng
dc.subject.otherelectrophileeng
dc.subject.otherhydrogeneng
dc.subject.otherruthenium complexeng
dc.subject.othertransition elementeng
dc.subject.otherunclassified drugeng
dc.subject.otherchemical bondeng
dc.subject.otherchemical structureeng
dc.subject.othercycloadditioneng
dc.subject.otherelectroneng
dc.subject.othernucleophilicityeng
dc.subject.otherultraviolet irradiationeng
dc.title(BB)-Carboryne Complex of Ruthenium: Synthesis by Double B-H Activation at a Single Metal Centereng
dc.typeArticleeng
dc.typeTexteng
tib.accessRightsopenAccesseng
wgl.contributorIFWDeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
jacs-6b05172-1.pdf
Size:
2.39 MB
Format:
Adobe Portable Document Format
Description:
Download
Collections
Chemie