Bis(dimethyl sulfoxide)hydridobis(triphenylphosphane)cobalt(I)

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dc.bibliographicCitation.issue8
dc.bibliographicCitation.journalTitleActa Crystallographica Section E: Structure Reports Onlineeng
dc.bibliographicCitation.volume66eng
dc.contributor.authorHapke, M.
dc.contributor.authorWeding, N.
dc.contributor.authorSpannenberg, A.
dc.date.accessioned2020-08-11T08:32:48Z
dc.date.available2020-08-11T08:32:48Z
dc.date.issued2010
dc.description.abstractThe title compound, [CoH(C18H15P)2(C 2H6OS)2], was synthesized by the reaction of chloridotris(triphenyl-phosphane)cobalt(I), [ClCo(PPh3)3], in the presence of one equivalent potassium hydridotris(pyrazol-yl)borate in dimethyl sulfoxide. The structure displays a distorted trigonal-pyramidally coordinated cobalt(I) atom, with two phosphane ligands and one DMSO ligand in the equatorial plane. The coordination is completed by one further DMSO ligand and the anionic hydride in the axial positions.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://doi.org/10.34657/4049
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/5420
dc.language.isoengeng
dc.publisherChester : International Union of Crystallographyeng
dc.relation.doihttps://doi.org/10.1107/S1600536810029466
dc.relation.issn1600-5368
dc.rights.licenseCC BY 4.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/eng
dc.subject.ddc540eng
dc.subject.otherCrystal structureeng
dc.subject.otherChemistryeng
dc.subject.otherCrystallographyeng
dc.titleBis(dimethyl sulfoxide)hydridobis(triphenylphosphane)cobalt(I)eng
dc.typeArticleeng
dc.typeTexteng
tib.accessRightsopenAccesseng
wgl.contributorLIKATeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
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