Selective Acceptorless Dehydrogenation of Primary Amines to Imines by Core-Shell Cobalt Nanoparticles
dc.bibliographicCitation.firstPage | 7501 | eng |
dc.bibliographicCitation.issue | 19 | eng |
dc.bibliographicCitation.journalTitle | Angewandte Chemie : a journal of the Gesellschaft Deutscher Chemiker : International edition | eng |
dc.bibliographicCitation.lastPage | 7507 | eng |
dc.bibliographicCitation.volume | 59 | eng |
dc.contributor.author | Cui, Xinjiang | |
dc.contributor.author | Li, Wu | |
dc.contributor.author | Junge, Kathrin | |
dc.contributor.author | Fei, Zhaofu | |
dc.contributor.author | Beller, Matthias | |
dc.contributor.author | Dyson, Paul J. | |
dc.date.accessioned | 2021-09-02T09:34:52Z | |
dc.date.available | 2021-09-02T09:34:52Z | |
dc.date.issued | 2020 | |
dc.description.abstract | Core–shell nanocatalysts are attractive due to their versatility and stability. Here, we describe cobalt nanoparticles encapsulated within graphitic shells prepared via the pyrolysis of a cationic poly-ionic liquid (PIL) with a cobalt(II) chloride anion. The resulting material has a core–shell structure that displays excellent activity and selectivity in the self-dehydrogenation and hetero-dehydrogenation of primary amines to their corresponding imines. Furthermore, the catalyst exhibits excellent activity in the synthesis of secondary imines from substrates with various reducible functional groups (C=C, C≡C and C≡N) and amino acid derivatives. © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. | eng |
dc.description.version | publishedVersion | eng |
dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/6663 | |
dc.identifier.uri | https://doi.org/10.34657/5710 | |
dc.language.iso | eng | eng |
dc.publisher | Weinheim : Wiley-VCH | eng |
dc.relation.doi | https://doi.org/10.1002/anie.201915526 | |
dc.relation.essn | 1521-3773 | |
dc.relation.issn | 0570-0833 | |
dc.relation.issn | 1433-7851 | |
dc.rights.license | CC BY-NC 4.0 Unported | eng |
dc.rights.uri | https://creativecommons.org/licenses/by-nc/4.0/ | eng |
dc.subject.ddc | 540 | eng |
dc.subject.other | amines | eng |
dc.subject.other | cobalt | eng |
dc.subject.other | dehydrogenation | eng |
dc.subject.other | heterogeneous catalysis | eng |
dc.subject.other | imines | eng |
dc.title | Selective Acceptorless Dehydrogenation of Primary Amines to Imines by Core-Shell Cobalt Nanoparticles | eng |
dc.type | Article | eng |
dc.type | Text | eng |
tib.accessRights | openAccess | eng |
wgl.contributor | LIKAT | eng |
wgl.subject | Chemie | eng |
wgl.type | Zeitschriftenartikel | eng |
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