Highly active and selective photochemical reduction of CO2 to CO using molecular-defined cyclopentadienone iron complexes

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dc.bibliographicCitation.date2016eng
dc.bibliographicCitation.firstPage8393eng
dc.bibliographicCitation.issue54eng
dc.bibliographicCitation.lastPage8396eng
dc.bibliographicCitation.volume52eng
dc.contributor.authorRosas-Hernández, Alonso
dc.contributor.authorAlsabeh, Pamela G.
dc.contributor.authorBarsch, Enrico
dc.contributor.authorJunge, Hernrik
dc.contributor.authorLudwig, Ralf
dc.contributor.authorBeller, Matthias
dc.date.accessioned2022-06-24T06:12:31Z
dc.date.available2022-06-24T06:12:31Z
dc.date.issued2015
dc.description.abstractHerein, we report highly active (cyclopentadienone)iron–tricarbonyl complexes for CO2 photoreduction using visible light with an Ir complex as photosensitizer and TEOA as electron/proton donor. Turnover numbers (TON) of ca. 600 (1 h) with initial turnover frequencies (TOF) up to 22.2 min−1 were observed. Operando FTIR measurements allowed for the proposal of a plausible mechanism for catalyst activation.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/9259
dc.identifier.urihttps://doi.org/10.34657/8297
dc.language.isoengeng
dc.publisherCambridge : Soc.eng
dc.relation.doihttps://doi.org/10.1039/c6cc01671e
dc.relation.essn1364-548X
dc.relation.ispartofseriesChemical communications : ChemComm 51 (2016), Nr. 54eng
dc.rights.licenseCC BY-NC 3.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by-nc/3.0/eng
dc.subjectcarbon dioxideeng
dc.subjectcyclopentadienone iron complexeng
dc.subjectiron complexeng
dc.subjectunclassified drugeng
dc.subjectcatalysteng
dc.subjecthydrogenationeng
dc.subjectinfrared spectroscopyeng
dc.subjectlighteng
dc.subjectphotochemistryeng
dc.subjectquantum yieldeng
dc.subjectreaction timeeng
dc.subjectturnover numbereng
dc.subject.ddc540eng
dc.titleHighly active and selective photochemical reduction of CO2 to CO using molecular-defined cyclopentadienone iron complexeseng
dc.typearticleeng
dc.typeTexteng
dcterms.bibliographicCitation.journalTitleChemical communications : ChemCommeng
tib.accessRightsopenAccesseng
wgl.contributorLIKATeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
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