Highly active and selective photochemical reduction of CO2 to CO using molecular-defined cyclopentadienone iron complexes

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dc.bibliographicCitation.date2016eng
dc.bibliographicCitation.firstPage8393eng
dc.bibliographicCitation.issue54eng
dc.bibliographicCitation.journalTitleChemical communications : ChemCommeng
dc.bibliographicCitation.lastPage8396eng
dc.bibliographicCitation.volume52eng
dc.contributor.authorRosas-Hernández, Alonso
dc.contributor.authorAlsabeh, Pamela G.
dc.contributor.authorBarsch, Enrico
dc.contributor.authorJunge, Hernrik
dc.contributor.authorLudwig, Ralf
dc.contributor.authorBeller, Matthias
dc.date.accessioned2022-06-24T06:12:31Z
dc.date.available2022-06-24T06:12:31Z
dc.date.issued2015
dc.description.abstractHerein, we report highly active (cyclopentadienone)iron–tricarbonyl complexes for CO2 photoreduction using visible light with an Ir complex as photosensitizer and TEOA as electron/proton donor. Turnover numbers (TON) of ca. 600 (1 h) with initial turnover frequencies (TOF) up to 22.2 min−1 were observed. Operando FTIR measurements allowed for the proposal of a plausible mechanism for catalyst activation.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/9259
dc.identifier.urihttps://doi.org/10.34657/8297
dc.language.isoengeng
dc.publisherCambridge : Soc.eng
dc.relation.doihttps://doi.org/10.1039/c6cc01671e
dc.relation.essn1364-548X
dc.rights.licenseCC BY-NC 3.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by-nc/3.0/eng
dc.subject.ddc540eng
dc.subject.othercarbon dioxideeng
dc.subject.othercyclopentadienone iron complexeng
dc.subject.otheriron complexeng
dc.subject.otherunclassified drugeng
dc.subject.othercatalysteng
dc.subject.otherhydrogenationeng
dc.subject.otherinfrared spectroscopyeng
dc.subject.otherlighteng
dc.subject.otherphotochemistryeng
dc.subject.otherquantum yieldeng
dc.subject.otherreaction timeeng
dc.subject.otherturnover numbereng
dc.titleHighly active and selective photochemical reduction of CO2 to CO using molecular-defined cyclopentadienone iron complexeseng
dc.typeArticleeng
dc.typeTexteng
tib.accessRightsopenAccesseng
wgl.contributorLIKATeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
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