Low temperature isolation of a dinuclear silver complex of the cyclotetraphosphane [ClP(μ-PMes*)]2
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Date
Volume
45
Issue
2
Journal
Dalton transactions : a journal of inorganic chemistry, including bioinorganic, organometallic, and solid-state chemistry
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London : Soc.
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Abstract
The reaction of the cyclotetraphosphane [ClP(μ-PMes*)]2 (1, Mes* = 2,4,6-tri-tert-butylphenyl) with Ag[Al(ORF)4] (RF = CH(CF3)2) resulted in a labile, dinuclear silver complex of 1, which eliminates AgCl above −30 °C. Its properties were investigated by spectroscopic methods, single crystal X-ray diffraction and DFT calculations.
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CC BY 3.0 Unported