Low temperature isolation of a dinuclear silver complex of the cyclotetraphosphane [ClP(μ-PMes*)]2
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Date
2015
Volume
45
Issue
2
Journal
Dalton transactions : a journal of inorganic chemistry, including bioinorganic, organometallic, and solid-state chemistry
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Book Title
Publisher
London : Soc.
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Abstract
The reaction of the cyclotetraphosphane [ClP(μ-PMes*)]2 (1, Mes* = 2,4,6-tri-tert-butylphenyl) with Ag[Al(ORF)4] (RF = CH(CF3)2) resulted in a labile, dinuclear silver complex of 1, which eliminates AgCl above −30 °C. Its properties were investigated by spectroscopic methods, single crystal X-ray diffraction and DFT calculations.
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Citation
Bresien, J., Schulz, A., & Villinger, A. (2015). Low temperature isolation of a dinuclear silver complex of the cyclotetraphosphane [ClP(μ-PMes*)]2 (London : Soc.). London : Soc. https://doi.org//10.1039/c5dt03928b
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CC BY 3.0 Unported