The effect of supported MoOX structures on the reaction pathways of propene formation in the metathesis of ethylene and 2-butene

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dc.bibliographicCitation.firstPage9060eng
dc.bibliographicCitation.issue65eng
dc.bibliographicCitation.journalTitleChemical Communicationseng
dc.bibliographicCitation.volume50eng
dc.contributor.authorHahn, T.
dc.contributor.authorKondratenko, E.V.
dc.contributor.authorLinke, D.
dc.date.accessioned2020-09-11T12:52:55Z
dc.date.available2020-09-11T12:52:55Z
dc.date.issued2014
dc.description.abstractThe kind of surface MoOX structures on Al2O3–SiO2 was found to determine propene selectivity in the metathesis of ethylene and 2-butene. Compared to isolated tetrahedral MoOX species, their polymerized octahedral counterparts show significantly lower activity for isomerisation of 2- to 1-butene thus hindering non-selective metathesis of these butenes. In addition, they reveal higher ability to engage ethylene in propene formation.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://doi.org/10.34657/4261
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/5632
dc.language.isoengeng
dc.publisherCambridge : RSCeng
dc.relation.doihttps://doi.org/10.1039/c4cc01827c
dc.relation.issn1359-7345
dc.rights.licenseCC BY 3.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by/3.0/eng
dc.subject.ddc540eng
dc.subject.otherbutaneeng
dc.subject.otherethyleneeng
dc.subject.otherpropyleneeng
dc.subject.otherarticleeng
dc.subject.othercatalysteng
dc.subject.otherchemical reactioneng
dc.subject.otherchemical structureeng
dc.subject.otherdimerizationeng
dc.subject.otherisomerizationeng
dc.subject.othermetathesiseng
dc.subject.otherpolymerizationeng
dc.subject.otherpressureeng
dc.subject.otherreaction analysiseng
dc.subject.othersurface propertyeng
dc.titleThe effect of supported MoOX structures on the reaction pathways of propene formation in the metathesis of ethylene and 2-buteneeng
dc.typeArticleeng
dc.typeTexteng
tib.accessRightsopenAccesseng
wgl.contributorLIKATeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
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