Ultrafast inter-ionic charge transfer of transition-metal complexes mapped by femtosecond x-ray powder diffraction

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dc.bibliographicCitation.firstPage5046eng
dc.bibliographicCitation.journalTitleEPJ Web of Conferenceseng
dc.bibliographicCitation.lastPage1033eng
dc.bibliographicCitation.volume41eng
dc.contributor.authorZamponi, F.
dc.contributor.authorFreyer, B.
dc.contributor.authorJuvé, V.
dc.contributor.authorStingl, J.
dc.contributor.authorWoerner, M.
dc.contributor.authorChergui, M.
dc.contributor.authorElsaesser, T.
dc.date.accessioned2020-09-25T12:04:57Z
dc.date.available2020-09-25T12:04:57Z
dc.date.issued2013
dc.description.abstractTransient electron density maps are derived from x-ray diffraction patterns of photoexcited [Fe(bpy)3]2+(PF6 -)2 powder. Upon photoexcitation, the 5T 2 quintet state reveals a charge transfer from the PF 6- ions and from the Fe atoms to neighboring bpy units. The charge transfer from the Fe points to a partial and weak charge-transfer character of this state.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://doi.org/10.34657/4349
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/5720
dc.language.isoengeng
dc.publisherLes Ulis : EDP Scienceseng
dc.relation.doihttps://doi.org/10.1051/epjconf/20134105046
dc.relation.issn2101-6275
dc.rights.licenseCC BY-NC 2.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by-nc/2.0/eng
dc.subject.ddc530eng
dc.subject.otherx-ray diffraction patternseng
dc.subject.otherphotoexcitationeng
dc.subject.othertransient electron density mapseng
dc.titleUltrafast inter-ionic charge transfer of transition-metal complexes mapped by femtosecond x-ray powder diffractioneng
dc.typeArticleeng
dc.typeTexteng
tib.accessRightsopenAccesseng
wgl.contributorMBIeng
wgl.subjectPhysikeng
wgl.typeZeitschriftenartikeleng
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