Determination of side products in the photocatalytic generation of hydrogen with copper photosensitizers by resonance Raman spectroelectrochemistry

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dc.bibliographicCitation.firstPage105801eng
dc.bibliographicCitation.issue107eng
dc.bibliographicCitation.lastPage105805eng
dc.bibliographicCitation.volume6eng
dc.contributor.authorZhang, Ying
dc.contributor.authorHeberle, Martin
dc.contributor.authorWächtler, Maria
dc.contributor.authorKarnahl, Michael
dc.contributor.authorDietzek, Benjamin
dc.date.accessioned2022-06-24T07:30:44Z
dc.date.available2022-06-24T07:30:44Z
dc.date.issued2016
dc.description.abstractA combination of UV-Vis and resonance Raman spectroscopy in conjunction with electrochemistry is employed to reveal the nature of a side product formed when using heteroleptic Cu(I)-photosensitizers [(P^P)Cu(N^N)]+ for photocatalytic hydrogen generation. It is shown that homoleptic [Cu(N^N)2]+ complexes are formed under oxidative conditions confirming a proposed deactivation pathway.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/9272
dc.identifier.urihttps://doi.org/10.34657/8310
dc.language.isoengeng
dc.publisherLondon : RSC Publishingeng
dc.relation.doihttps://doi.org/10.1039/c6ra21469j
dc.relation.essn2046-2069
dc.relation.ispartofseriesRSC Advances : an international journal to further the chemical sciences 6 (2016), Nr. 107eng
dc.rights.licenseCC BY 3.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by/3.0/eng
dc.subjectCopper compoundseng
dc.subjectPhotosensitizerseng
dc.subjectSpectroelectrochemistryeng
dc.subjectDeactivation pathwayseng
dc.subjectHeterolepticeng
dc.subjectOxidative conditionseng
dc.subjectPhoto-catalyticeng
dc.subjectPhotocatalytic hydrogeneng
dc.subjectResonance Raman spectroelectrochemistrieseng
dc.subjectResonance Raman spectroscopyeng
dc.subjectSide productseng
dc.subjectHydrogen productioneng
dc.subject.ddc540eng
dc.titleDetermination of side products in the photocatalytic generation of hydrogen with copper photosensitizers by resonance Raman spectroelectrochemistryeng
dc.typearticleeng
dc.typeTexteng
dcterms.bibliographicCitation.journalTitleRSC Advances : an international journal to further the chemical scienceseng
tib.accessRightsopenAccesseng
wgl.contributorIPHTeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
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