Determination of side products in the photocatalytic generation of hydrogen with copper photosensitizers by resonance Raman spectroelectrochemistry

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dc.bibliographicCitation.firstPage105801eng
dc.bibliographicCitation.issue107eng
dc.bibliographicCitation.journalTitleRSC Advances : an international journal to further the chemical scienceseng
dc.bibliographicCitation.lastPage105805eng
dc.bibliographicCitation.volume6eng
dc.contributor.authorZhang, Ying
dc.contributor.authorHeberle, Martin
dc.contributor.authorWächtler, Maria
dc.contributor.authorKarnahl, Michael
dc.contributor.authorDietzek, Benjamin
dc.date.accessioned2022-06-24T07:30:44Z
dc.date.available2022-06-24T07:30:44Z
dc.date.issued2016
dc.description.abstractA combination of UV-Vis and resonance Raman spectroscopy in conjunction with electrochemistry is employed to reveal the nature of a side product formed when using heteroleptic Cu(I)-photosensitizers [(P^P)Cu(N^N)]+ for photocatalytic hydrogen generation. It is shown that homoleptic [Cu(N^N)2]+ complexes are formed under oxidative conditions confirming a proposed deactivation pathway.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/9272
dc.identifier.urihttps://doi.org/10.34657/8310
dc.language.isoengeng
dc.publisherLondon : RSC Publishingeng
dc.relation.doihttps://doi.org/10.1039/c6ra21469j
dc.relation.essn2046-2069
dc.rights.licenseCC BY 3.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by/3.0/eng
dc.subject.ddc540eng
dc.subject.otherCopper compoundseng
dc.subject.otherPhotosensitizerseng
dc.subject.otherSpectroelectrochemistryeng
dc.subject.otherDeactivation pathwayseng
dc.subject.otherHeterolepticeng
dc.subject.otherOxidative conditionseng
dc.subject.otherPhoto-catalyticeng
dc.subject.otherPhotocatalytic hydrogeneng
dc.subject.otherResonance Raman spectroelectrochemistrieseng
dc.subject.otherResonance Raman spectroscopyeng
dc.subject.otherSide productseng
dc.subject.otherHydrogen productioneng
dc.titleDetermination of side products in the photocatalytic generation of hydrogen with copper photosensitizers by resonance Raman spectroelectrochemistryeng
dc.typeArticleeng
dc.typeTexteng
tib.accessRightsopenAccesseng
wgl.contributorIPHTeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
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