A crystalline anionic complex of scandium nitride endometallofullerene: Experimental observation of single-bonded (Sc3N@Ih-C80−)2 dimers
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Date
2016
Volume
52
Issue
71
Journal
Series Titel
Book Title
Publisher
Cambridge : Royal Society of Chemistry
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Abstract
Reduction of scandium nitride clusterfullerene, Sc3N@Ih-C80, by sodium fluorenone ketyl in the presence of cryptand[2,2,2] allows the crystallization of the {cryptand2,2,2}2(Sc3N@Ih-C80−)2·2.5C6H4Cl2 (1) salt. The Sc3N@Ih-C80˙− radical anions are dimerized to form single-bonded (Sc3N@Ih-C80−)2 dimers.
Description
Keywords
anion, cryptand, dimer, fullerene derivative, . scandium, triscandium nitride clusterfullerene, unclassified drug, absorption, Article, chemical structure, crystal crystal structure, crystallization, dimerization, isomer, X ray diffraction
Citation
Konarev, D. V., Zorina, L. V., Khasanov, S. S., Popov, A. A., Otsuka, A., Yamochi, H., et al. (2016). A crystalline anionic complex of scandium nitride endometallofullerene: Experimental observation of single-bonded (Sc3N@Ih-C80−)2 dimers. 52(71). https://doi.org//10.1039/C6CC05550H
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CC BY-NC 3.0 Unported