Tetracarbonyl[bis(diphenylphosphanyl)-tetramethyldisiloxane- κ 2 P,P′]chromium(0)
| dc.bibliographicCitation.issue | 2 | |
| dc.bibliographicCitation.volume | 68 | eng |
| dc.contributor.author | Peulecke, N. | |
| dc.contributor.author | Müller, B.H. | |
| dc.contributor.author | Spannenberg, A. | |
| dc.contributor.author | Rosenthal, U. | |
| dc.date.accessioned | 2020-09-06T07:58:38Z | |
| dc.date.available | 2020-09-06T07:58:38Z | |
| dc.date.issued | 2012 | |
| dc.description.abstract | The title compound, [Cr(C 28H 32OP 2Si 2)(CO) 4], was obtained by the ligand-exchange reaction of Cr(CO) 6 with (Ph 2PSiMe 2) 2O in refluxing toluene. The CrC 4P 2 coordination geometry is distorted octa-hedral, with a P - Cr - P bite angle of 99.22 (4)°. | eng |
| dc.description.version | publishedVersion | eng |
| dc.identifier.uri | https://doi.org/10.34657/4209 | |
| dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/5580 | |
| dc.language.iso | eng | eng |
| dc.publisher | Chester : International Union of Crystallography | eng |
| dc.relation.doi | https://doi.org/10.1107/S1600536812000219 | |
| dc.relation.ispartofseries | Acta Crystallographica Section E: Structure Reports Online 68 (2012), 2 | eng |
| dc.relation.issn | 1600-5368 | |
| dc.rights.license | CC BY 4.0 Unported | eng |
| dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | eng |
| dc.subject | data-to-parameter ratio = 17.2 | eng |
| dc.subject | mean σ(C-C) = 0.003 Å | eng |
| dc.subject | R factor = 0.035 | eng |
| dc.subject | single-crystal X-ray study | eng |
| dc.subject | T = 150 K | eng |
| dc.subject | wR factor = 0.059 | eng |
| dc.subject.ddc | 540 | eng |
| dc.title | Tetracarbonyl[bis(diphenylphosphanyl)-tetramethyldisiloxane- κ 2 P,P′]chromium(0) | eng |
| dc.type | article | eng |
| dc.type | Text | eng |
| dcterms.bibliographicCitation.journalTitle | Acta Crystallographica Section E: Structure Reports Online | eng |
| tib.accessRights | openAccess | eng |
| wgl.contributor | LIKAT | eng |
| wgl.subject | Chemie | eng |
| wgl.type | Zeitschriftenartikel | eng |