Novel ruthenium-catalyst for hydroesterification of olefins with formates

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Profir2014.pdf(773.2 KB)
Date
2014
Authors
Volume
12
Issue
36
Journal
Organic and Biomolecular Chemistry
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Book Title
Publisher
London [u.a.] : Royal Society of Chemistry
Link to publishers version
https://doi.org/10.1039/c4ob01246a
Abstract

An alternative ruthenium-based catalyst for the hydroesterification of olefins with formates is reported. The good activity of our system is ensured by the use of a bidentate P,N-ligand and ruthenium dodecacarbonyl. A range of formates can be used for selective alkoxycarbonylation of aromatic olefins. In addition, the synthesis of selected aliphatic esters is realized. The proposed active ruthenium complex has been isolated and characterized.

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URI
https://doi.org/10.34657/4508
 https://oa.tib.eu/renate/handle/123456789/5879
Citation
Profir, I., Beller, M., & Fleischer, I. (2014). Novel ruthenium-catalyst for hydroesterification of olefins with formates (London [u.a.] : Royal Society of Chemistry). London [u.a.] : Royal Society of Chemistry. https://doi.org//10.1039/c4ob01246a
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Chemie
License
CC BY 3.0 Unported
https://creativecommons.org/licenses/by/3.0/