Synthesis of Polyampholyte Janus-like Microgels by Coacervation of Reactive Precursors in Precipitation Polymerization
dc.bibliographicCitation.firstPage | 1248 | eng |
dc.bibliographicCitation.issue | 3 | eng |
dc.bibliographicCitation.journalTitle | Angewandte Chemie : a journal of the Gesellschaft Deutscher Chemiker : International edition | eng |
dc.bibliographicCitation.lastPage | 1255 | eng |
dc.bibliographicCitation.volume | 59 | eng |
dc.contributor.author | Xu, Wenjing | |
dc.contributor.author | Rudov, Andrey | |
dc.contributor.author | Oppermann, Alex | |
dc.contributor.author | Wypysek, Sarah | |
dc.contributor.author | Kather, Michael | |
dc.contributor.author | Schroeder, Ricarda | |
dc.contributor.author | Richtering, Walter | |
dc.contributor.author | Potemkin, Igor I. | |
dc.contributor.author | Wöll, Dominik | |
dc.contributor.author | Pich, Andrij | |
dc.date.accessioned | 2021-07-30T06:51:45Z | |
dc.date.available | 2021-07-30T06:51:45Z | |
dc.date.issued | 2020 | |
dc.description.abstract | Controlling the distribution of ionizable groups of opposite charge in microgels is an extremely challenging task, which could open new pathways to design a new generation of stimuli-responsive colloids. Herein, we report a straightforward approach for the synthesis of polyampholyte Janus-like microgels, where ionizable groups of opposite charge are located on different sides of the colloidal network. This synthesis approach is based on the controlled self-assembly of growing polyelectrolyte microgel precursors during the precipitation polymerization process. We confirmed the morphology of polyampholyte Janus-like microgels and demonstrate that they are capable of responding quickly to changes in both pH and temperature in aqueous solutions. © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. | eng |
dc.description.version | publishedVersion | eng |
dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/6446 | |
dc.identifier.uri | https://doi.org/10.34657/5493 | |
dc.language.iso | eng | eng |
dc.publisher | Weinheim : Wiley-VCH | eng |
dc.relation.doi | https://doi.org/10.1002/anie.201910450 | |
dc.relation.essn | 1521-3773 | |
dc.relation.issn | 0570-0833 | |
dc.relation.issn | 1433-7851 | |
dc.rights.license | CC BY 4.0 Unported | eng |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | eng |
dc.subject.ddc | 540 | eng |
dc.subject.other | Janus-like microgels | eng |
dc.subject.other | molecular modeling | eng |
dc.subject.other | polyampholyte | eng |
dc.subject.other | responsive materials | eng |
dc.subject.other | self-assembly | eng |
dc.title | Synthesis of Polyampholyte Janus-like Microgels by Coacervation of Reactive Precursors in Precipitation Polymerization | eng |
dc.type | Article | eng |
dc.type | Text | eng |
tib.accessRights | openAccess | eng |
wgl.contributor | DWI | eng |
wgl.subject | Chemie | eng |
wgl.type | Zeitschriftenartikel | eng |
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