Tetracarbonyl-2κ4C-[μ-5-methyl-1,1,3-triphenyl-2-(propan-2-yl)-2,4-diaza-1,3-diphosphahexan-4-ido-1κN4:2κP1,P3](N,N,N′,N′-tetramethylethane-1,2-diamine-1κ2N,N′)lithiummolybdenum
dc.bibliographicCitation.firstPage | x181149 | eng |
dc.bibliographicCitation.lastPage | 89 | eng |
dc.bibliographicCitation.volume | 3 | eng |
dc.contributor.author | Höhne, Martha | |
dc.contributor.author | Spannenberg, Anke | |
dc.contributor.author | Müller, Bernd H. | |
dc.contributor.author | Peulecke, Normen | |
dc.contributor.author | Rosenthal, Uwe | |
dc.date.accessioned | 2020-11-26T09:36:48Z | |
dc.date.available | 2020-11-26T09:36:48Z | |
dc.date.issued | 2018 | |
dc.description.abstract | The title complex, [LiMo(C6H16N2)(C24H29N2P2)(CO)4], contains a distorted octahedrally coordinated molybdenum centre bearing a lithiated P,P′-cis-chelating PNPN ligand, which results in a nearly planar four-membered metallacycle. The Li atom is coordinated by one equivalent tetramethylethylenediamine. In the crystal, molecules are linked via weak C—H...O interactions, forming a chain along the b-axis direction. | eng |
dc.description.sponsorship | Leibniz_Fonds | eng |
dc.description.version | publishedVersion | eng |
dc.identifier.uri | https://doi.org/10.34657/4642 | |
dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/6013 | |
dc.language.iso | eng | eng |
dc.publisher | Chester : IUCr | eng |
dc.relation.doi | https://doi.org/10.1107/S2414314618011495 | |
dc.relation.ispartofseries | IUCrData 3 (2018) | eng |
dc.relation.issn | 2414-3146 | |
dc.rights.license | CC BY 4.0 Unported | eng |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | eng |
dc.subject | crystal structure | eng |
dc.subject | molybdenum | eng |
dc.subject | diphosphazane ligand | eng |
dc.subject.ddc | 540 | eng |
dc.title | Tetracarbonyl-2κ4C-[μ-5-methyl-1,1,3-triphenyl-2-(propan-2-yl)-2,4-diaza-1,3-diphosphahexan-4-ido-1κN4:2κP1,P3](N,N,N′,N′-tetramethylethane-1,2-diamine-1κ2N,N′)lithiummolybdenum | ger |
dc.type | article | eng |
dc.type | Text | eng |
dcterms.bibliographicCitation.journalTitle | IUCrData | eng |
tib.accessRights | openAccess | eng |
wgl.contributor | LIKAT | eng |
wgl.subject | Chemie | eng |
wgl.type | Zeitschriftenartikel | eng |
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