Gallium and Indium Alkoxides with Hydride, Cyclopentadienediide and Copper(I) tert-Butoxide as further Components

dc.bibliographicCitation.firstPage1272eng
dc.bibliographicCitation.journalTitleZeitschrift für Anorganische und Allgemeine Chemieeng
dc.bibliographicCitation.volume645eng
dc.contributor.authorVeith, M.
dc.contributor.authorSumma, D.
dc.contributor.authorAnnel, U.
dc.contributor.authorHuch, V.
dc.date.accessioned2020-01-14T06:56:41Z
dc.date.available2020-01-14T06:56:41Z
dc.date.issued2019
dc.description.abstractGallium hydride stabilized by the base quinonuclidine reacts with acetone under addition of the Ga-H function to the carbon–oxygen double bond yielding (HGa)5(OiPr)8O (1) as isolable compound. (HGa)5(OiPr)8O may be formally split in to four entities of HGa(OiPr)2 and one entity HGaO. The inner atomic skeleton of 1 is a novel Ga5O9 heterocluster with gallium atoms occupying the corners of a distorted trigonal bi-pyramid, an oxygen atom in the center and the remaining alcoholate oxygen atoms bridging eight of the nine edges of the bi-pyramid (X-ray diffraction analysis). Potassium indium alkoxide KIn(OtBu)4 has been used to synthesize several new compounds like In4(OtBu)8(C5H4)2 (2), (py)2CuIn(OtBu)4 (3), and [CuIn(OtBu)4]2 (4) by reaction with TiCl2cp2 (2) and CuCl (3, 4). All compounds were characterized by spectroscopic means and by X-ray structure analyses revealing novel polycyclic structures. © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://doi.org/10.34657/112
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/4841
dc.language.isoengeng
dc.publisherWeinheim : Wiley-VCHeng
dc.relation.doihttps://doi.org/10.1002/zaac.201900240
dc.rights.licenseCC BY 4.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/eng
dc.subject.ddc540eng
dc.subject.otherAlkoxi gallates and indateseng
dc.subject.otherCopper-indium alkoxideseng
dc.subject.otherGa–O cageseng
dc.subject.otherIndium fulveneseng
dc.subject.otherX-ray diffractioneng
dc.titleGallium and Indium Alkoxides with Hydride, Cyclopentadienediide and Copper(I) tert-Butoxide as further Componentseng
dc.typeArticleeng
dc.typeTexteng
tib.accessRightsopenAccesseng
wgl.contributorINMeng
wgl.subjectIngenieurwissenschafteneng
wgl.typeZeitschriftenartikeleng
Files
Original bundle
Now showing 1 - 1 of 1
Loading...
Thumbnail Image
Name:
Gallium and Indium Alkoxides with Hydride.pdf
Size:
2.8 MB
Format:
Adobe Portable Document Format
Description: