Plasmon induced deprotonation of 2-mercaptopyridine

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Date
2020
Volume
145
Issue
6
Journal
Analyst
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Publisher
Cambridge : Royal Society of Chemistry
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Abstract

Surface plasmons can provide a novel route to induce and simultaneously monitor selective bond formation and breakage. Here pH-induced protonation, followed by plasmon-induced deprotonation of 2-mercaptopyridine was investigated using surface- and tip-enhanced Raman scattering (SERS and TERS). A large difference in the deprotonation rate between SERS and TERS will be demonstrated and discussed with respect to hot-spot distribution. © 2020 The Royal Society of Chemistry.

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Singh P., Deckert-Gaudig T., Zhang Z., & Deckert V. (2020). Plasmon induced deprotonation of 2-mercaptopyridine (Cambridge : Royal Society of Chemistry). Cambridge : Royal Society of Chemistry. https://doi.org//10.1039/c9an01970g
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CC BY-NC 3.0 Unported