Accessing heavy allyl-analogous [(TerN)2E]− (E = Sb, Bi) ions and their reactivity towards ECl3

Hinz, Alexander; Schulz, Axel; Villinger, Alexander

Accessing heavy allyl-analogous [(TerN)2E]− (E = Sb, Bi) ions and their reactivity towards ECl3

Files

Accessing_heavy_allyl-analogous.pdf(1.73 MB)

Date

2015

Authors

Hinz, Alexander

Schulz, Axel

Villinger, Alexander

Volume

51

Issue

57

Journal

Chemical communications : ChemComm

Publisher

Cambridge : Soc.

Link to publishers version

https://doi.org/10.1039/c5cc04355g

Abstract

The attempted preparation of the biradicaloid [E(μ-NTer)]2 (E = Sb, Bi) yielded salts of the anion [(TerN)2E]−. These heteroatom allyl analogues could be further utilized in the reaction with pnictogen(III) chlorides to form the first 1,3-dichloro-1-bisma-3-stiba-2,4-diazane [ClSb(μ-NTer)2BiCl].

URI

https://oa.tib.eu/renate/handle/123456789/9180
https://doi.org/10.34657/8218

Citation

Hinz, A., Schulz, A., & Villinger, A. (2015). Accessing heavy allyl-analogous [(TerN)2E]− (E = Sb, Bi) ions and their reactivity towards ECl3 (Cambridge : Soc.). Cambridge : Soc. https://doi.org//10.1039/c5cc04355g

Collections

Chemie

License

CC BY 3.0 Unported

https://creativecommons.org/licenses/by/3.0/

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