Iron/N-doped graphene nano-structured catalysts for general cyclopropanation of olefins

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dc.bibliographicCitation.firstPage6217eng
dc.bibliographicCitation.issue24eng
dc.bibliographicCitation.journalTitleChemical scienceeng
dc.bibliographicCitation.lastPage6221eng
dc.bibliographicCitation.volume11eng
dc.contributor.authorSarkar, Abhijnan
dc.contributor.authorFormenti, Dario
dc.contributor.authorFerretti, Francesco
dc.contributor.authorKreyenschulte, Carsten
dc.contributor.authorBartling, Stephan
dc.contributor.authorJunge, Kathrin
dc.contributor.authorBeller, Matthias
dc.contributor.authorRagaini, Fabio
dc.date.accessioned2021-09-07T06:51:21Z
dc.date.available2021-09-07T06:51:21Z
dc.date.issued2020
dc.description.abstractThe first examples of heterogeneous Fe-catalysed cyclopropanation reactions are presented. Pyrolysis of in situ-generated iron/phenanthroline complexes in the presence of a carbonaceous material leads to specific supported nanosized iron particles, which are effective catalysts for carbene transfer reactions. Using olefins as substrates, cyclopropanes are obtained in high yields and moderate diastereoselectivities. The developed protocol is scalable and the activity of the recycled catalyst after deactivation can be effectively restored using an oxidative reactivation protocol under mild conditions. This journal is © The Royal Society of Chemistry.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/6720
dc.identifier.urihttps://doi.org/10.34657/5767
dc.language.isoengeng
dc.publisherCambridge : RSCeng
dc.relation.doihttps://doi.org/10.1039/d0sc01650k
dc.relation.essn2041-6539
dc.relation.issn2041-6520
dc.rights.licenseCC BY 3.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by/3.0/eng
dc.subject.ddc540eng
dc.subject.otherCatalyst activityeng
dc.subject.otherIron compoundseng
dc.subject.otherOlefinseng
dc.subject.otherCarbene transfereng
dc.subject.otherCarbonaceous materialseng
dc.subject.otherCyclopropanationeng
dc.subject.otherCyclopropanation reactioneng
dc.subject.otherDiastereoselectivitieseng
dc.subject.otherHigh yieldeng
dc.subject.otherIron Particleseng
dc.subject.otherNano-structured catalysteng
dc.subject.otherNanocatalystseng
dc.titleIron/N-doped graphene nano-structured catalysts for general cyclopropanation of olefinseng
dc.typeArticleeng
dc.typeTexteng
tib.accessRightsopenAccesseng
wgl.contributorLIKATeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
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