Synthesis and crystallographic characterization of [2,2-bis­(η5-penta­methyl­cyclo­penta­dien­yl)-3,4-bis(tri­methyl­sil­yl)-2-zircona­furan-5-one-κO5]triisobutyl­aluminium

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dc.bibliographicCitation.firstPage566
dc.bibliographicCitation.issue4
dc.bibliographicCitation.lastPage568
dc.bibliographicCitation.volume74
dc.contributor.authorBurlakov, Vladimir V.
dc.contributor.authorBogdanov, Vyacheslav S.
dc.contributor.authorArndt, Perdita
dc.contributor.authorSpannenberg, Anke
dc.contributor.authorRosenthal, Uwe
dc.contributor.authorBeweries, Torsten
dc.contributor.authorShur, Vladimir B.
dc.date.accessioned2023-01-19T09:43:50Z
dc.date.available2023-01-19T09:43:50Z
dc.date.issued2018-3-27
dc.description.abstractThe crystal structure of the title zwitterionic zirconocene complex containing a furan­one unit, [AlZr(C10H15)2(C4H9)3(C9H18O2Si2)], is reported. On reacting a zircona­furan­one with two equivalents of HAl(i-Bu)2, disproportionation of the Lewis acid results in the formation of a triiso­butyl­aluminium fragment, Al(i-Bu)3, which coordinates to the exocyclic carbonyl O atom of the zircona­furan­one ring. Single-crystal X-ray diffraction reveals that the zircona­furan­one ring remains intact with coordination of the aluminium to the exocyclic O atom. One of the i-butyl groups is disordered over two sets of sites, with an occupancy ratio of 0.731 (3):0.269 (3).eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/10922
dc.identifier.urihttp://dx.doi.org/10.34657/9948
dc.language.isoeng
dc.publisherChester : International Union of Crystallography
dc.relation.doihttps://doi.org/10.1107/s2056989018004759
dc.relation.essn2056-9890
dc.relation.ispartofseriesActa crystallographica : Section E, Crystallographic communications
dc.rights.licenseCC BY 2.0 UK
dc.rights.urihttps://creativecommons.org/licenses/by/2.0/uk/
dc.subjectcrystal structureeng
dc.subjecttriisobutylaluminiumeng
dc.subjectzirconium metalloceneeng
dc.subjectzwitterionic enolate complexeng
dc.subject.ddc530
dc.titleSynthesis and crystallographic characterization of [2,2-bis­(η5-penta­methyl­cyclo­penta­dien­yl)-3,4-bis(tri­methyl­sil­yl)-2-zircona­furan-5-one-κO5]triisobutyl­aluminiumeng
dc.typearticleeng
dc.typeTexteng
dcterms.bibliographicCitation.journalTitleActa crystallographica : Section E, Crystallographic communications
local.doifilter.overrideja
tib.accessRightsopenAccesseng
wgl.contributorLIKAT
wgl.subjectPhysikger
wgl.typeZeitschriftenartikelger
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