Bis(μ2-isopropylimido-κ2 N:N)bis[(η5-cyclopentadienyl)(ethenolato-κO)titanium(IV)]
| dc.bibliographicCitation.issue | 1 | |
| dc.bibliographicCitation.volume | 70 | eng |
| dc.contributor.author | Haehnel, M. | |
| dc.contributor.author | Spannenberg, A. | |
| dc.contributor.author | Rosenthal, U. | |
| dc.date.accessioned | 2020-09-06T07:58:34Z | |
| dc.date.available | 2020-09-06T07:58:34Z | |
| dc.date.issued | 2014 | |
| dc.description.abstract | The title dinuclear half-sandwich complex, [CpTi(OCH=CH2) (μ2-N-iPr)]2 (Cp = cyclopentadienyl; iPr = isopropyl), was obtained from the reaction of Cp2TiCl2, n-butyllithium and isopropylamine in tetrahydrofuran. Each TiIV atom is coordinated by one Cp ligand, one vinyloxy unit and two bridging imido groups in a strongly distorted tetrahedral geometry. There are two half molecules in the asymmetric unit, such that whole molecules being generated by inversion symmetry. | eng |
| dc.description.version | publishedVersion | eng |
| dc.identifier.uri | https://doi.org/10.34657/4199 | |
| dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/5570 | |
| dc.language.iso | eng | eng |
| dc.publisher | Chester : International Union of Crystallography | eng |
| dc.relation.doi | https://doi.org/10.1107/S1600536813033072 | |
| dc.relation.ispartofseries | Acta Crystallographica Section E: Structure Reports Online 70 (2014), 1 | eng |
| dc.relation.issn | 1600-5368 | |
| dc.rights.license | CC BY 4.0 Unported | eng |
| dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | eng |
| dc.subject | chemistry | eng |
| dc.subject | crystal structures | eng |
| dc.subject.ddc | 540 | eng |
| dc.title | Bis(μ2-isopropylimido-κ2 N:N)bis[(η5-cyclopentadienyl)(ethenolato-κO)titanium(IV)] | eng |
| dc.type | article | eng |
| dc.type | Text | eng |
| dcterms.bibliographicCitation.journalTitle | Acta Crystallographica Section E: Structure Reports Online | eng |
| local.doifilter.override | ja | |
| tib.accessRights | openAccess | eng |
| wgl.contributor | LIKAT | eng |
| wgl.subject | Chemie | eng |
| wgl.type | Zeitschriftenartikel | eng |