CC BY 3.0 DEBenne, DarjaRüssel, Christian2024-01-052024-01-052003https://oa.tib.eu/renate/handle/123456789/13947https://doi.org/10.34657/12977Melts with the basic compositions I6R2O - 10CaO - 74SiO2 (R = lithium, sodium, potassium), 20Na2O ∙ xCaO ∙ (80-x)SiO2 (x = 0, 10, 20), 16Na2O - 10MgO - 74SiO2 and 15Na2O - 85SiO2 all doped with 0.25 mol% SnO2 were studied using square-wave voltammetry at temperatures in the range from 1000 to 1600 °C. Over a wide temperature range, the measured peak potentials decreased linearly with temperature. The peak potentials are most negative for the 15Na2O - 85SiO2 melt and least negative for the 16Na2O - 10MgO - 74SiO2 melt. The effect of the glass composition on the Sn2+/Sn4+ redox equilibrium is much less pronounced than in the case of the Fe2+/Fe3+ equilibrium.enghttps://creativecommons.org/licenses/by/3.0/de/660Article