CC BY-NC-ND 4.0 UnportedMorales Torres, GalinaBehrens, StephanMichalik, DirkSelent, DetlefSpannenberg, AnkeLühr, SusanDyballa, Katrin MarieFranke, RobertBörner, Armin2023-01-192023-01-192017-1-23https://oa.tib.eu/renate/handle/123456789/10936https://doi.org/10.34657/9962A series of diphosphoramidites has been synthetized with a piperazine, homopiperazine, and an acyclic 1,2-diamine unit in the backbone. New compounds were tested alongside related N-acyl phosphoramidites as ligands in the Rh-catalyzed hydroformylation of n-octenes to investigate their influence on the activity and regioselectivity. A subsequent study of their hydrolysis stability revealed that the most stable ligands induced the highest activity in the catalytic reaction.enghttps://creativecommons.org/licenses/by-nc-nd/4.0/540diphosphoramiditeshydroformylationregioselectivityrhodiumstructure–activity relationshipsArticle