This document may be downloaded, read, stored and printed for your own use within the limits of § 53 UrhG but it may not be distributed via the internet or passed on to external parties.Dieses Dokument darf im Rahmen von § 53 UrhG zum eigenen Gebrauch kostenfrei heruntergeladen, gelesen, gespeichert und ausgedruckt, aber nicht im Internet bereitgestellt oder an Außenstehende weitergegeben werden.Dreyer, WolfgangGuhlke, ClemensMüller, Rüdiger2018-08-012019-06-2820182198-5855https://doi.org/10.34657/2092https://oa.tib.eu/renate/handle/123456789/2268We propose a modeling framework for magnetizable, polarizable, elastic, viscous, heat conducting, reactive mixtures in contact with interfaces. To this end we first introduce bulk and surface balance equations that contain several constitutive quantities. For further modeling the constitutive quantities, we formulate constitutive principles. They are based on an axiomatic introduction of the entropy principle and the postulation of Galilean symmetry. We apply the proposed formalism to derive constitutive relations in a rather abstract setting. For illustration of the developed procedure, we state an explicit isothermal material model for liquid electrolyte|metal electrode interfaces in terms of free energy densities in the bulk and on the surface. Finally we give a survey of recent advancements in the understanding of electrochemical interfaces that were based on this model.application/pdfeng510Bulk-surface electro-thermodynamicsentropy principleconstitutive modelingelectrochemistryReport