CC BY-NC 3.0 UnportedAppiah, ClementSiefermann, Katrin R.Jorewitz, MarcelBarqawi, HaithamBinder, Wolfgang H.2022-05-102022-05-102016https://oa.tib.eu/renate/handle/123456789/8903https://doi.org/10.34657/7941A novel and efficient strategy in obtaining series of mono- and bi-armed azobenzene-containing poly(ε-caprolactone)s is described, starting from a commercially available azobenzene dye via azide/alkyne-“click”-reactions. The attachment of alkyne-telechelic poly(ε-caprolactone)s (1 kDa and 3 kDa), followed by chromatographic separation, allowed the attachment of either one or two PCl-chains to either side of the azobenzene-dye. The resulting mono- and bi-armed photo-switchable polymers are fully characterized by 2D-NMR techniques and show a high thermal stability. Additionally liquid chromatography at critical conditions (LCCC) coupled to ESI-TOF allowed us to prove the presence of either one or two polymer chains affixed onto the central azobenzene dye.enghttps://creativecommons.org/licenses/by-nc/3.0/540ChainsChromatographyLiquid chromatographyNuclear magnetic resonance spectroscopyPolymersAzobenzene dyesChromatographic separationsEfficient strategyHigh thermal stabilityLiquid chromatography at critical condition (LCCC)Photo-switchablePoly (epsiloncaprolactone)Synthesis and characterizationsAzobenzeneArticle