CC BY 4.0 UnportedHapke, M.Spannenberg, A.2020-08-112020-08-112008https://doi.org/10.34657/4061https://oa.tib.eu/renate/handle/123456789/5432The title compound, [Co(C5H5)(C18H15P)2]·0.2C7H8·0.25C6H14, was synthesized by the reaction of cobaltocene, Cp2Co, with elemental lithium in tetra-hydro-furan in the presence of two equivalents of PPh3. The mol-ecular structure displays a cobalt(I) center in a distorted trigonal-planar coordination environment, with one Cp and two phosphane ligands. There are two crystallographically independent mol-ecules in the asymmetric unit besides the disordered solvent molecules.enghttps://creativecommons.org/licenses/by/4.0/540Crystal structureChemistryCrystallography(μ5-Cyclo-penta-dien-yl)bis-(triphenyl-phosphane)cobalt(I) -toluene-n-hexane (1/0.20/0.25)Article