Browsing by Author "Testrich, Holger"
Now showing 1 - 6 of 6
Results Per Page
Sort Options
- ItemEnergy Flux Characterisation of Atmospheric Pressure Plasma Spray Torches with Passive Thermal Probes(Boston, Mass. : Springer, 2022) Reck, Kristian A.; Hansen, Luka; Stummer, Maximilian; Kewitz, Thorben; Testrich, Holger; Hinterer, Andreas; Foest, Rüdiger; Kersten, HolgerPassive thermal probes were applied on two different plasma spraying devices to gain a detailed understanding of the energy flux towards the substrate under atmospheric pressure. The challenge of very high thermal load was solved by using an advanced time-resolved measuring and evaluation technique. The combination with a controlled movement of the jets allowed to obtain insightful radial profiles. The energy flux to the substrate changes linearly to the electrical input power. When adding diatomic gases (H2/N2) to the gas mixture the energy flux increases significantly, suggesting a more efficient energy transport. For increasing the axial distance, the energy flux shows a quadratic reduction. The obtained radial profiles are exemplarily utilized to show the inhomogeneous effect of powder injection on the energy flux distribution.
- ItemLocal Inflammatory Response after Intramuscularly Implantation of Anti-Adhesive Plasma-Fluorocarbon-Polymer Coated Ti6AI4V Discs in Rats(Basel : MDPI, 2021) Koppe, Charlotte; Hoene, Andreas; Walschus, Uwe; Finke, Birgit; Testrich, Holger; Pohl, Christopher; Brandt, Nico; Patrzyk, Maciej; Meichsner, Jürgen; Nebe, Barbara; Schlosser, MichaelOrthopaedic implants and temporary osteosynthesis devices are commonly based on Titanium (Ti). For short-term devices, cell-material contact should be restricted for easy removal after bone healing. This could be achieved with anti-adhesive plasma-fluorocarbon-polymer (PFP) films created by low-temperature plasma processes. Two different PFP thin film deposition techniques, microwave (MW) and radiofrequency (RF) discharge plasma, were applied to receive smooth, hydrophobic surfaces with octafluoropropane (C3F8) or hexafluorohexane (C6F6) as precursors. This study aimed at examining the immunological local tissue reactions after simultaneous intramuscular implantation of four different Ti samples, designated as MW-C3F8, MW-C6F6, RF-C3F8 and Ti-controls, in rats. A differentiated morphometric evaluation of the inflammatory reaction was conducted by immunohistochemical staining of CD68+ macrophages, CD163+ macrophages, MHC class II-positive cells, T lymphocytes, CD25+ regulatory T lymphocytes, NK cells and nestin-positive cells in cryosections of surrounding peri-implant tissue. Tissue samples were obtained on days 7, 14 and 56 for investigating the acute and chronical inflammation (n = 8 rats/group). Implants with a radiofrequency discharge plasma (RF-C3F8) coating exhibited a favorable short- and long-term immune/inflammatory response comparable to Ti-controls. This was also demonstrated by the significant decrease in pro-inflammatory CD68+ macrophages, possibly downregulated by significantly increasing regulatory T lymphocytes.
- ItemPlasma Spraying of Kaolinite for Preparing Reactive Alumino-Silicate Glass Coatings(Weinheim : Wiley-VCH, 2022) Warr, Laurence N.; Wolff, Thorben; Testrich, Holger; Grathoff, Georg; Kruth, Angela; Foest, RüdigerThermally treated kaolinite is used to develop a range of alumino-silicate-based precursor materials but its behavior during plasma spraying has not been well-researched. In this study, two types of kaolinite samples were investigated in the form of low defect (KGa-1b) and high defect (KGa-2) varieties. The extreme temperatures of the plasma stream (up to 20 000 K) induced flash melting to produce a highly porous alumino-silicate glass without any crystallization of new Al−Si oxide minerals. The glass is comprised largely of intact or deformed spheres (average diameters 1.14–1.44 μm), which indicates rapid quenching and solidification before impact. The subspherical structures contain up to 40 % closed pore space caused by the rapid escape of water during melting. The low-density, porous alumino-silicate glass coatings with predicted specific surface areas (>0.95 m2/g) and hardnesses >1.8 GPa represent a potentially reactive but physically stable substrate ideal for further chemical functionalization.
- ItemQuantification of osseointegration of plasma-polymer coated titanium alloyed implants by means of microcomputed tomography versus histomorphometry(New York [u.a.] : Hindawi, 2015) Gabler, Carolin; Zietz, Carmen; Bieck, Richard; Göhler, Rebecca; Lindner, Tobias; Haenle, Maximilian; Finke, Birgit; Meichsner, Jürgen; Testrich, Holger; Nowottnick, Mathias; Frerich, Bernhard; Bader, RainerA common method to derive both qualitative and quantitative data to evaluate osseointegration of implants is histomorphometry. The present study describes a new image reconstruction algorithm comparing the results of bone-to-implant contact (BIC) evaluated by means of µCT with histomorphometry data. Custom-made conical titanium alloyed (Ti6Al4V) implants were inserted in the distal tibial bone of female Sprague-Dawley rats. Different surface configurations were examined: Ti6Al4V implants with plasma-polymerized allylamine (PPAAm) coating and plasma-polymerized ethylenediamine (PPEDA) coating as well as implants without surface coating. After six weeks postoperatively, tibiae were explanted and BIC was determined by µCT (3D) and afterwards by histomorphometry (2D). In comparison to uncoated Ti6Al4V implants demonstrating low BIC of 32.4% (histomorphometry) and 51.3% (µCT), PPAAm and PPEDA coated implants showed a nonsignificant increase in BIC (histomorphometry: 45.7% and 53.5% and µCT: 51.8% and 62.0%, resp.). Mean BIC calculated by µCT was higher for all surface configurations compared to BIC detected by histomorphometry. Overall, a high correlation coefficient of 0.70 () was found between 3D and 2D quantification of BIC. The μCT analysis seems to be suitable as a nondestructive and accurate 3D imaging method for the evaluation of the bone-implant interface.
- ItemSelf-Consistent Cathode–Plasma Coupling and Role of the Fluid Flow Approach in Torch Modeling(Boston, Mass. : Springer, 2021) Baeva, Margarita; Zhu, Tao; Kewitz, Thorben; Testrich, Holger; Foest, RüdigerA two-dimensional and stationary magnetohydrodynamic model of a plasma spray torch operated with argon is developed to predict the plasma properties in a steady operating mode. The model couples a submodel of a refractory cathode and its non-equilibrium boundary layer to a submodel of the plasma in local thermodynamic equilibrium in a self-consistent manner. The Navier–Stokes equations for a laminar and compressible flow are solved in terms of low and high Mach number numerical approaches. The results show that the Mach number can reach values close to one. Simulations are performed for electric currents of 600 A and 800 A, and gas flow rates of 40, 60, and 80 NLPM. The plasma parameters obtained by the two approaches differ, and the differences become more pronounced for higher currents and gas flow rates. The arc voltage, the electric power, and the thermal efficiency from both the low and high Mach number models of the plasma agree well with experimental findings for a current of 600 A and a flow rate of 40 NLPM. For higher currents and gas flow rates, the results of the low and high Mach number models gradually differ and underline the greater appropriateness of the high Mach number model.
- ItemSynthesis of hydroxy-sodalite/cancrinite zeolites from calcite-bearing kaolin for the removal of heavy metal ions in aqueous media(Basel : MDPI, 2019) Esaifan, Muayad; Warr, Laurence N.; Gratho, Georg; Meyer, Tammo; Schafmeister, Maria-Theresia; Kruth, Angela; Testrich, HolgerA hydroxy-sodalite/cancrinite zeolite composite was synthesized from low-grade calcite-bearing kaolin by hydrothermal alkali-activation method at 160 °C for 6 h. The effect of calcite addition on the formation of the hydroxy-sodalite/cancrinite composite was investigated using artificial mixtures. The chemical composition and crystal morphology of the synthesized zeolite composite were characterized by X-ray powder diffraction, infrared spectroscopy, scanning electron microscopy, and N2 adsorption/desorption analyses. The average specific surface area is around 17–20 m2·g−1, whereas the average pore size lies in the mesoporous range (19–21 nm). The synthesized zeolite composite was used as an adsorbent for the removal of heavy metals in aqueous solutions. Batch experiments were employed to study the influence of adsorbent dosage on heavy metal removal efficiency. Results demonstrate the effective removal of significant quantities of Cu, Pb, Ni, and Zn from aqueous media. A comparative study of synthesized hydroxy-sodalite and hydroxy-sodalite/cancrinite composites revealed the latter was 16–24% more efficient at removing heavy metals from water. The order of metal uptake efficiency for these zeolites was determined to be Pb > Cu > Zn > Ni. These results indicate that zeolite composites synthesized from natural calcite-bearing kaolin materials could represent effective and low-cost adsorbents for heavy metal removal using water treatment devices in regions of water shortage.