[1-Dimethylsilyl-2-phenyl-3-(η5-tetramethylcyclopentadienyl) prop-1-en-1-ylκC1](n5-pentamethylcyclopentadienyl)- titanium(III)
dc.bibliographicCitation.issue | 11 | |
dc.bibliographicCitation.volume | 65 | eng |
dc.contributor.author | Lamač, M. | |
dc.contributor.author | Spannenberg, A. | |
dc.contributor.author | Arndt, P. | |
dc.contributor.author | Rosenthal, U. | |
dc.date.accessioned | 2020-08-11T08:32:48Z | |
dc.date.available | 2020-08-11T08:32:48Z | |
dc.date.issued | 2009 | |
dc.description.abstract | The title compound, [Ti(C10H15)(C20H 26Si)], was obtained from the reaction of [Ti{5: 1-C5Me4(CH2)}(5-C 5Me5)] with the alkynylsilane PhC2SiMe 2H. The complex crystallizes with two independent mol-ecules in the asymmetric unit, which differ in the conformation of the propenyl unit, resulting in their having opposite helicity. No inter-molecular inter-actions or inter-actions involving the Si- H bond are present. The observed geometrical parameters are unexceptional compared to known structures of the same type. | eng |
dc.description.version | publishedVersion | eng |
dc.identifier.uri | https://doi.org/10.34657/4052 | |
dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/5423 | |
dc.language.iso | eng | eng |
dc.publisher | Chester : International Union of Crystallography | eng |
dc.relation.doi | https://doi.org/10.1107/S1600536809044845 | |
dc.relation.ispartofseries | Acta Crystallographica Section E: Structure Reports Online 65 (2009), 11 | eng |
dc.relation.issn | 1600-5368 | |
dc.rights.license | CC BY 4.0 Unported | eng |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | eng |
dc.subject | Crystal structure | eng |
dc.subject | Chemistry | eng |
dc.subject | Crystallography | eng |
dc.subject.ddc | 540 | eng |
dc.title | [1-Dimethylsilyl-2-phenyl-3-(η5-tetramethylcyclopentadienyl) prop-1-en-1-ylκC1](n5-pentamethylcyclopentadienyl)- titanium(III) | eng |
dc.type | article | eng |
dc.type | Text | eng |
dcterms.bibliographicCitation.journalTitle | Acta Crystallographica Section E: Structure Reports Online | eng |
tib.accessRights | openAccess | eng |
wgl.contributor | LIKAT | eng |
wgl.subject | Chemie | eng |
wgl.type | Zeitschriftenartikel | eng |
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